Nitrogen-rich heterocycles

被引:149
作者
Singh, Rajendra P.
Ga, Haixiang
Meshri, Dayal T.
Shreeve, Jean'ne M.
机构
[1] Adv Res Chem Inc, Catoosa, OK 74015 USA
[2] Univ Idaho, Dept Chem, Moscow, ID 83844 USA
来源
HIGH ENERGY DENSITY MATERIALS | 2007年 / 125卷
关键词
nitrogen rich; energetic; heterocycles; heat of formation; density; thermochemistry;
D O I
10.1007/430_2006_055
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Many advantages accrue from nitrogen-rich heterocyclic compounds compared to traditional molecular energetic compounds. Utilization of heterocyclic nitrogen-containing cations and anions in energetic salts gives rise to lower vapor pressures, higher heats of formation and higher densities. Additionally, smaller amounts of hydrogen and carbon contribute to a better oxygen balance than normally is found with their carbocyclic analogues. Nitrogen-rich compounds are promising high energetic materials that may be more acceptable than their alternatives for both industrial and military uses since a higher percentage of their decomposition products will be dinitrogen.
引用
收藏
页码:35 / 83
页数:49
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