Hybrid Nanomaterials by Surface Grafting of Synthetic Polypeptides Using N-Carboxyanhydride (NCA) Polymerization

被引：45
作者：
Borase, Tushar [1 ]
Heise, Andreas [2 ]
机构：
[1] Dublin City Univ, Sch Chem Sci, Dublin 9, Ireland
[2] Royal Coll Surgeons Ireland, Dept Pharmaceut & Med Chem, Dublin 2, Ireland
来源：
ADVANCED MATERIALS | 2016年 / 28卷 / 27期
基金：
爱尔兰科学基金会;
关键词：
hybrid materials; nanomaterials; polymer brushes; polypeptides; surface grafting; RING-OPENING POLYMERIZATION; VAPOR-DEPOSITION-POLYMERIZATION; SELF-ASSEMBLED MONOLAYERS; WALLED CARBON NANOTUBES; SILICA NANOPARTICLES; INITIATED POLYMERIZATION; BLOCK COPOLYPEPTIDES; HELIX ORIENTATION; FACILE SYNTHESIS; FILMS;
D O I：
10.1002/adma.201504474
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The interaction of materials with their environment is largely dictated by interfacial phenomena. Polymers are very versatile materials to modulate material interfaces to provide functionality, stability and compatibility. A class of polymers that can close the gap between fully synthetic and natural macromolecules are polypeptides derived from N-carboxyanhydride (NCA) polymerization. Recent advances in using this technique to create biomimetic interfaces and hybrid materials are highlighted, with special emphasis on nanomaterials.
引用
收藏
页码：5725 / 5731
页数：7
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