Preparative routes to organozinc reagents used for organic synthesis

被引：15

作者：

Nakamura, M ^{[1
]}

Nakamura, E ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

来源：

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 1998年 / 56卷 / 08期

关键词：

organozinc reagent; preparative methods; C-C bond forming reactions; polyfunctionalized organometallics; selective organometallic reagent; oxidative zincation; transmetalation; halogen-zinc exchange;

D O I：

10.5059/yukigoseikyokaishi.56.632

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Organozinc reagents have become extremely important synthetic tools in recent years, and the useful and practical preparative routes to such reagents have been reviewed. The methods have been classified into four broad categories, (1) oxidative zincation method, (2) transmetalation method, (3) halogen-zinc exchange, and (4) others. Each categories are subdivided according to the type of organic groups on the zinc atom (alkyl, alkenyl, etc.).

引用

页码：632 / 644

页数：13

共 99 条

[11]

FLANKLAND E, 1849, LIEBIGS ANN CHEM, V71, P171

[12] A CONVENIENT PREPARATION OF FUNCTIONALIZED ARYLZINC COMPOUNDS BY THE REACTION OF ZINC/SILVER-GRAPHITE WITH ARYL IODIDES [J].

FURSTNER, A ;

SINGER, R ;

KNOCHEL, P .

TETRAHEDRON LETTERS, 1994, 35 (07) :1047-1050

[13] CHEMISTRY OF AND WITH HIGHLY REACTIVE METALS [J].

FURSTNER, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1993, 32 (02) :164-189

[14]

FURSTNER A, 1989, SYNTHESIS-STUTTGART, P571

[15] A NOVEL ROUTE TO CYCLOPROPANES FROM OLEFINS [J].

FURUKAWA, J ;

KAWABATA, N ;

NISHIMURA, J .

TETRAHEDRON LETTERS, 1966, (28) :3353-+

[16]

Furukawa J., 1974, Adv. Organomet. Chem, V12, P83

[17] STEREOSELECTIVE AND REGIOSELECTIVE GENERATION OF ALKENYLZINC REAGENTS VIA TITANIUM-CATALYZED HYDROZINCATION OF INTERNAL ACETYLENES [J].

GAO, Y ;

HARADA, K ;

HATA, T ;

URABE, H ;

SATO, F .

JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (02) :290-291

[18] FIRST PRACTICAL HYDROZINCATION OF DIENES CATALYZED BY CP(2)TICL(2) - GENERATION OF ALLYLZINC REAGENT AND ITS REACTION WITH CARBONYL-COMPOUNDS [J].

GAO, YA ;

URABE, H ;

SATO, F .

JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (19) :5521-5523

[19]

GAUDEMAR M, 1962, B SOC CHIM FR, P974

[20] DIRECT FORMATION OF ALKYLZINC CHLORIDES USING A NEW ACTIVE ZINC [J].

HANSON, M ;

RIEKE, RD .

SYNTHETIC COMMUNICATIONS, 1995, 25 (01) :101-104

← 1 2 3 4 5 6 7 8 9 10 →