Selective capture of volatile iodine using amorphous molecular organic solids

被引:38
作者
Huang, Pin-Shen [1 ]
Kuo, Chih-Hong [1 ]
Hsieh, Chang-Chih [1 ]
Horng, Yih-Chern [1 ]
机构
[1] Natl Changhua Univ Educ, Dept Chem, Changhua 50058, Taiwan
关键词
COORDINATION POLYMER; CAGE COMPOUNDS; FRAMEWORK; CHANNELS; CRYSTAL; COMPLEX; BOND;
D O I
10.1039/c2cc17716a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A simple shape-persistent organic molecular container is capable of selective absorption and storage of I-2(g) over water vapor and NO gas even in its amorphous solid state. In addition, the strongly associated I-2 can be efficiently released from the charged container in organic solvents under ambient conditions.
引用
收藏
页码:3227 / 3229
页数:3
相关论文
共 35 条
[1]   Zinc saccharate: A robust, 3D coordination network with two types of isolated, parallel channels, one hydrophilic and the other hydrophobic [J].
Abrahams, BF ;
Moylan, M ;
Orchard, SD ;
Robson, R .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (16) :1848-1851
[2]   A SPECTROPHOTOMETRIC INVESTIGATION OF THE INTERACTION OF IODINE WITH AROMATIC HYDROCARBONS [J].
BENESI, HA ;
HILDEBRAND, JH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1949, 71 (08) :2703-2707
[3]   Alfred Werner revisited: The coordination chemistry of anions [J].
Bowman-James, K .
ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (08) :671-678
[4]   Trapping Guests within a Nanoporous Metal-Organic Framework through Pressure-Induced Amorphization [J].
Chapman, Karena W. ;
Sava, Dorina F. ;
Halder, Gregory J. ;
Chupas, Peter J. ;
Nenoff, Tina M. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (46) :18583-18585
[5]   Radioactive Iodine Capture in Silver-Containing Mordenites through Nanoscale Silver Iodide Formation [J].
Chapman, Karena W. ;
Chupas, Peter J. ;
Nenoff, Tina M. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (26) :8897-+
[6]   Porous, crystalline, covalent organic frameworks [J].
Côté, AP ;
Benin, AI ;
Ockwig, NW ;
O'Keeffe, M ;
Matzger, AJ ;
Yaghi, OM .
SCIENCE, 2005, 310 (5751) :1166-1170
[7]   Permeability of a seemingly nonporous crystal formed by a discrete metallocyclic complex [J].
Dobrzanska, L ;
Lloyd, GO ;
Raubenheimer, HG ;
Barbour, LJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (03) :698-699
[8]   Nuclear Waste Management in the United States-Starting Over [J].
Ewing, Rodney C. ;
von Hippel, Frank N. .
SCIENCE, 2009, 325 (5937) :151-152
[9]  
Haefner D. R., 2007, METHODS GAS PHASE CA, DOI [DOI 10.2172/911962, 10.2172/911962]
[10]   Porous Organic Cage Nanocrystals by Solution Mixing [J].
Hasell, Tom ;
Chong, Samantha Y. ;
Jelfs, Kim E. ;
Adams, Dave J. ;
Cooper, Andrew I. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (01) :588-598