Bifunctional Metal Organic Framework Catalysts for Multistep Reactions: MOF-Cu(BTC)-[Pd] Catalyst for One-Pot Heteroannulation of Acetylenic Compounds

被引：95
作者：
Arnanz, Avelina [2 ]
Pintado-Sierra, Mercedes [3 ]
Corma, Avelino [1 ]
Iglesias, Marta [2 ]
Sanchez, Felix [3 ]
机构：
[1] UPV CSIC, Inst Tecnol Quim, Valencia 46022, Spain
[2] CSIC, Inst Ciencia Mat Madrid, E-28049 Madrid, Spain
[3] CSIC, Inst Quim Organ Gen, E-28006 Madrid, Spain
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2012年 / 354卷 / 07期
关键词：
bifunctional metal organic frameworks (MOFs); copper-palladium catalysis; coupling-cyclization; isoindoles; tandem recations; THERMAL-STABILITY; REUSABLE CATALYST; MOFS; SEPARATION; LIGAND; GREEN; AZIDE; PALLADIUM; EFFICIENT; COPPER(I);
D O I：
10.1002/adsc.201100503
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A bifunctional metal organic framework catalyst containing palladium and copper(II) benzene-1,3,5-tricarboxylate MOF-Cu(BTC)-[Pd] has been prepared. This catalyst enables the performance of the tandem Sonogashira/click reaction starting from 2-iodobenzylbromide, sodium azide and alkynes to produce 8H-[1,2,3]triazolo[5,1-a]isoindoles with good yields under mild reaction conditions.
引用
收藏
页码：1347 / 1355
页数：9
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