Bifunctional Metal Organic Framework Catalysts for Multistep Reactions: MOF-Cu(BTC)-[Pd] Catalyst for One-Pot Heteroannulation of Acetylenic Compounds

被引：97

作者：

Arnanz, Avelina ^{[2
]}

Pintado-Sierra, Mercedes ^{[3
]}

Corma, Avelino ^{[1
]}

Iglesias, Marta ^{[2
]}

Sanchez, Felix ^{[3
]}

机构：

[1] UPV CSIC, Inst Tecnol Quim, Valencia 46022, Spain

[2] CSIC, Inst Ciencia Mat Madrid, E-28049 Madrid, Spain

[3] CSIC, Inst Quim Organ Gen, E-28006 Madrid, Spain

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2012年 / 354卷 / 07期

关键词：

bifunctional metal organic frameworks (MOFs); copper-palladium catalysis; coupling-cyclization; isoindoles; tandem recations; THERMAL-STABILITY; REUSABLE CATALYST; MOFS; SEPARATION; LIGAND; GREEN; AZIDE; PALLADIUM; EFFICIENT; COPPER(I);

D O I：

10.1002/adsc.201100503

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A bifunctional metal organic framework catalyst containing palladium and copper(II) benzene-1,3,5-tricarboxylate MOF-Cu(BTC)-[Pd] has been prepared. This catalyst enables the performance of the tandem Sonogashira/click reaction starting from 2-iodobenzylbromide, sodium azide and alkynes to produce 8H-[1,2,3]triazolo[5,1-a]isoindoles with good yields under mild reaction conditions.

引用

页码：1347 / 1355

页数：9

共 78 条

[1] [Al4(OH)2(OCH3)4(H2N-bdc)3]•xH2O: A 12-Connected Porous Metal-Organic Framework with an Unprecedented Aluminum-Containing Brick [J].