Crystal structure of a 3D Ag(I) coordination polymer based on flexible bis(benzimidazole) and 5-nitroisophthalic acid co-ligands

被引：3
|
作者：
Zhang, X. [1 ]
Liu, L. [1 ]
Qin, L. [1 ]
Cui, G. H. [1 ]
机构：
[1] Hebei United Univ, Coll Chem Engn, Tangshan, Hebei Province, Peoples R China
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2015年 / 56卷 / 04期
关键词：
Ag(I) complex; 1,4-bis(5,6-dimethylbenzimidazol-1-yl) butane; crystal structure; CATALYTIC-PROPERTIES; SILVER(I); COMPLEXES; CHAIN; AG;
D O I：
10.1134/S0022476615040265
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new coordination polymer {[Ag-4(L)(3)(nip)(2)](H2O)} (n) (L = 1,4-bis(5,6-dimethylbenzimidazol-1-yl)butane, H(2)nip = 5-nitroisophthalic acid) is hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction. The complex features a 3D sqc117 supramolecular framework based on unique tetranuclear Ag(I) clusters which involve the ligand-supported Ag-Ag interactions.
引用
收藏
页码：777 / 781
页数：5
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