Crystal structure of a 3D Ag(I) coordination polymer based on flexible bis(benzimidazole) and 5-nitroisophthalic acid co-ligands

被引：3

作者：

Zhang, X. ^{[1
]}

Liu, L. ^{[1
]}

Qin, L. ^{[1
]}

Cui, G. H. ^{[1
]}

机构：

[1] Hebei United Univ, Coll Chem Engn, Tangshan, Hebei Province, Peoples R China

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2015年 / 56卷 / 04期

关键词：

Ag(I) complex; 1,4-bis(5,6-dimethylbenzimidazol-1-yl) butane; crystal structure; CATALYTIC-PROPERTIES; SILVER(I); COMPLEXES; CHAIN; AG;

D O I：

10.1134/S0022476615040265

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new coordination polymer {[Ag-4(L)(3)(nip)(2)](H2O)} (n) (L = 1,4-bis(5,6-dimethylbenzimidazol-1-yl)butane, H(2)nip = 5-nitroisophthalic acid) is hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction. The complex features a 3D sqc117 supramolecular framework based on unique tetranuclear Ag(I) clusters which involve the ligand-supported Ag-Ag interactions.

引用

页码：777 / 781

页数：5

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