Understanding methane aromatization on a Zn-modified high-silica zeolite

被引：148

作者：

Luzgin, Mikhail V. ^{[1
]}

Rogov, Vladimir A. ^{[1
]}

Arzumanov, Sergei S. ^{[1
]}

Toktarev, Alexander V. ^{[1
]}

Stepanov, Alexander G. ^{[1
]}

Parmon, Valentin N. ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, Novosibirsk 630090, Russia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 24期

关键词：

mass spectrometry; methane; NMR spectroscopy; reaction mechanisms; zeolites;

D O I：

10.1002/anie.200800317

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

It takes two: A high level of conversion of 13C atoms of methane into the products of methane/propane coaromatization on zeolite Zn/H-BEA has been demonstrated by 13C solid-state NMR spectroscopic analysis and GC-MS. The isotope-labeling experiments show the mechanism consists of the methylation of aromatic compounds formed from the propane followed by ring-expansion/contraction (see scheme). (Chemical Equation Presented). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4559 / 4562

页数：4

共 33 条

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