Conformational and intramolecular hydrogen-bonding properties of substituted dithia[3.3]metacyclophanes

被引:0
|
作者
Moriguchi, T [1 ]
Sakata, K [1 ]
Tsuge, A [1 ]
机构
[1] Kyushu Inst Technol, Fac Engn, Dept Chem, Tobata Ku, Kitakyushu, Fukuoka 804, Japan
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Conformational properties and intramolecular hydrogen-bondings of dithia[3.3]metacyclophanes carrying one or two amino group on their internal positions were studied by H-1-NMR, IR spectra and X-ray structural analyses. It was found out that intramolecular hydrogen-bonding network between amino proteins and bridge sulfur atoms is formed and it is closely related to the conformations of cyclophanes.
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页码:167 / 168
页数:2
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