Amino- and azidotrifluoromethylation of alkenes

被引：63

作者：

Tian, Yu ^{[1
,2
]}

Chen, Su ^{[3
]}

Gu, Qiang-Shuai ^{[2
]}

Lin, Jin-Shun ^{[2
]}

Liu, Xin-Yuan ^{[2
]}

机构：

[1] Harbin Inst Technol, Sch Chem & Chem Engn, Harbin 150080, Heilongjiang, Peoples R China

[2] South Univ Sci & Technol China, Dept Chem, Shenzhen 518055, Peoples R China

[3] Northwestern Univ, Dept Chem, 2145 Sheridan Rd, Evanston, IL 60208 USA

来源：

TETRAHEDRON LETTERS | 2018年 / 59卷 / 03期

基金：

中国国家自然科学基金;

关键词：

Aminotrifluoromethylation; Azidotrifluoromethylation; Alkene; Copper catalysis; Photoredox catalysis; COPPER-CATALYZED TRIFLUOROMETHYLATION; C-H FUNCTIONALIZATION; UNACTIVATED ALKENES; PHOTOREDOX CATALYSIS; RADICAL TRIFLUOROMETHYLATION; ALLYLIC ALCOHOLS; ROOM-TEMPERATURE; BOND FORMATION; INTRAMOLECULAR AMINOTRIFLUOROMETHYLATION; INTERMOLECULAR TRIFLUOROMETHYLAZIDATION;

D O I：

10.1016/j.tetlet.2017.12.034

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Trifluoromethylation of alkenes has long been the interest of synthetic chemists. It is not only because of the great importance of F-containing compounds, but also on account of the pleasure of cracking the challenges in methodology development in this field. In particular, amino- and azidotrifluoromethylation of alkenes have recently been developing in a fast speed. This digest mainly deals with this advancement in racemic copper- and photocatalyzed amino- and azidotrifluoromethylation of alkenes while giving special highlight on our recent breakthrough on the copper-catalyzed asymmetric aminotrifluoromethylation reaction. (C) 2017 Elsevier Ltd. All rights reserved.

引用

页码：203 / 215

页数：13

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