Nanolayered structures in photochromic crystal of 1,2-bis(2-methyl-5-p-methoxyphenyl-3-thienyl) perfluorocyclopentene

被引：0
|
作者：
Kobatake, S
Morimoto, M
Irie, M
机构：
[1] Osaka City Univ, Dept Appl & Bioappl Chem, Grad Sch Engn, Sumiyoshi Ku, Osaka 5588585, Japan
[2] Kyushu Univ, Dept Chem & Biochem, Grad Sch Engn, Higashi Ku, Fukuoka 812, Japan
来源：
MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2005年 / 431卷
关键词：
diarylethene; nanolayered structure; photochromism; single crystal;
D O I：
10.1080/15421400590947306
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A photochromic diarylethene, 1,2-bis(2-methyl-5-p-methoxyphenyl-3-thienyl)perfluorocyclopentene (1a), forms four kinds of polymorphic crystals by recrystallization from the hexane solution. X-ray crystallographic analysis of the needle crystals among four polymorphic forms indicated that the diarylethene is orientated into herringbone nanolayered structures. The crystal exhibited photochromism upon photoirradiation. Alternate nanolayered structures composed of open- and closed-ring isomers were formed by irradiation with polarized visible light after irradiation with ultraviolet light.
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页码：523 / 527
页数：5
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