Pseudo-C3-symmetric trisoxazolines as ligands in copper catalyzed enantioselective Diels-Alder reaction

被引：57

作者：

Zhou, J ^{[1
]}

Tang, Y ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2004年 / 2卷 / 03期

关键词：

D O I：

10.1039/b313796a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Air- and water-stable chiral catalyst trisoxazolines 4-6/Cu(ClO4)(2).6H(2)O have been used in the Diels-Alder reaction of cyclopentadiene with acryloyl-2-oxazolidinones or ketoesters. The reaction is carried out in air and up to 82% ee was achieved.

引用

页码：429 / 433

页数：5

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