Copper(II) and cadmium(II) complexes of mono-condensed N,O- or N,N,O-Donor ligands: synthesis, crystal structures, and antibacterial activity

被引:0
作者
Wang, Shiyi [1 ]
You, Zhonglu [1 ]
Qian, Heng-Yu [2 ]
机构
[1] Liaoning Normal Univ, Dept Chem & Chem Engn, Dalian, Peoples R China
[2] Zhengzhou Univ Light Ind, Sch Mat & Chem Engn, Key Lab Surface & Interface Sci Henan, Zhengzhou, Peoples R China
关键词
Schiff base; reduced Schiff base; copper complex; cadmium complex; crystal structure; antibacterial activity; SCHIFF-BASE LIGANDS; X-RAY; DERIVATIVES; NICKEL(II);
D O I
10.1080/24701556.2021.2025087
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Three new copper(II) and cadmium(II) complexes, [Cu(L-1)(2)] (1), [CuL2(N-3)] (2), and [Cd(L-3)(2)] (3), where L-1 = 2-bromo-4-chloro-6-cyclohexylaminomethylphenolate, L-2 = 2-bromo-4-chloro-6-[(2-morpholin-4-ylethylimino)methyl]phenolate, and L-3 = 2-bromo-4-chloro-6-[(3-morpholin-4-ylpropylimino)methyl]phenolate, have been prepared and structurally characterized by X-ray crystallography. The Cu atom in complex 1 is in tetrahedrally distorted square planar geometry. The Cu atom in complex 2 is in square planar geometry. The Cd atom in complex 3 is in octahedral geometry. The complexes exhibited effective activities against B. subtilis, S. aureus and E. coli.
引用
收藏
页码:287 / 292
页数:6
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