Hot-injection synthesis of iron/iron oxide core/shell nanoparticles for T2 contrast enhancement in magnetic resonance imaging

被引：57

作者：

Herman, David A. J. ^{[1
,2
]}

Ferguson, Peter ^{[3
]}

Cheong, Soshan ^{[1
,2
,4
]}

Hermans, Ian F. ^{[3
]}

Ruck, Ben J. ^{[1
,2
]}

Allan, Kathryn M. ^{[1
,2
]}

Prabakar, Sujay ^{[1
,2
]}

Spencer, John L. ^{[1
,2
]}

Lendrum, Conrad D. ^{[4
]}

Tilley, Richard. D. ^{[1
,2
]}

机构：

[1] Victoria Univ Wellington, Sch Chem & Phys Sci, Wellington, New Zealand

[2] Victoria Univ Wellington, MacDiarmid Inst Adv Mat & Nanotechnol, Wellington, New Zealand

[3] Malaghan Inst Med Res, Wellington, New Zealand

[4] Ind Res Ltd, Lower Hutt, New Zealand

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 32期

关键词：

IRON NANOPARTICLES; FUNCTIONALIZATION; STABILIZATION; OXIDATION;

D O I：

10.1039/c1cc13416g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Here we report a new, bench-top synthesis for iron/iron oxide core/shell nanoparticles via the thermal decomposition of Fe(eta(5)-C6H3Me4)(2). The iron/iron oxide core/shell nanoparticles are superparamagnetic at room temperature and show improved negative contrast in T-2-weighted MR imaging compared to pure iron oxides nanoparticles, and have a transverse relaxivity (r(2)) of 332 mM(-1) s(-1).

引用

页码：9221 / 9223

页数：3

共 31 条

[1] Stabilization and functionalization of iron oxide nanoparticles for biomedical applications
Amstad, Esther
Textor, Marcus
Reimhult, Erik
[J]. NANOSCALE, 2011, 3 (07) : 2819 - 2843
[2] Synthesis and Comparison of the Magnetic Properties of Iron Sulfide Spinel and Iron Oxide Spinel Nanocrystals
Beal, John H. L.
Prabakar, Sujay
Gaston, Nicola
Teh, Geok B.
Etchegoin, Pablo G.
Williams, Grant
Tilley, Richard D.
[J]. CHEMISTRY OF MATERIALS, 2011, 23 (10) : 2514 - 2517
[3] Simple Synthesis and Functionalization of Iron Nanoparticles for Magnetic Resonance Imaging
Cheong, Soshan
Ferguson, Peter
Feindel, Kirk W.
Hermans, Ian F.
Callaghan, Paul T.
Meyer, Claire
Slocombe, Angela
Su, Chia-Hao
Cheng, Fong-Yu
Yeh, Chen-Sheng
Ingham, Bridget
Toney, Michael F.
Tilley, Richard D.
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (18) : 4206 - 4209
[4] Safety and efficacy of meso-2,3-dimercaptosuccinic acid (DMSA) in children with elevated blood lead concentrations
Chisolm, JJ
[J]. JOURNAL OF TOXICOLOGY-CLINICAL TOXICOLOGY, 2000, 38 (04): : 365 - 375
[5] Nanoparticle assisted magnetic resonance imaging of the early reversible stages of amyloid β self-assembly
Choi, Jin-sil
Choi, Hyuck Jae
Jung, Dae Chul
Lee, Joo-Hyuk
Cheon, Jinwoo
[J]. CHEMICAL COMMUNICATIONS, 2008, (19) : 2197 - 2199
[6] SYNTHESIS, CHARACTERIZATION, AND DYNAMIC BEHAVIOR OF PSEUDOFERROCENE COMPLEXES
CLERK, MD
ZAWOROTKO, MJ
BORECKA, B
CAMERON, TS
HOOPER, DL
LINDEN, A
[J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1990, 68 (11): : 1923 - 1931
[7] Superlattices of iron nanocubes synthesized from Fe[N(SiMe3)2]2
Dumestre, F
Chaudret, B
Amiens, C
Renaud, P
Fejes, P
[J]. SCIENCE, 2004, 303 (5659) : 821 - 823
[8] Preparation and characterization of monodisperse Fe nanoparticles
Farrell, D
Majetich, SA
Wilcoxon, JP
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (40) : 11022 - 11030
[9] STRUCTURE, MAGNETIC CHARACTERIZATION, AND OXIDATION OF COLLOIDAL IRON DISPERSIONS
GRIFFITHS, CH
OHORO, MP
SMITH, TW
[J]. JOURNAL OF APPLIED PHYSICS, 1979, 50 (11) : 7108 - 7115
[10] Metallic Iron Nanoparticles for MRI Contrast Enhancement and Local Hyperthermia
Hacliipanayis, Coslas G.
Bonder, Michael J.
Balakrishanan, Srinivasan
Wang, Xiaoxia
Mao, Huio
Hadjipanayis, George C.
[J]. SMALL, 2008, 4 (11) : 1925 - 1929

← 1 2 3 4 →