Experimental investigation and thermodynamic assessment of the Al-Fe system

被引：37

作者：

Zienert, Tilo ^{[1
,2
]}

Fabrichnaya, Olga ^{[1
]}

机构：

[1] TU Bergakad Freiberg, Inst Mat Sci, Gustav Zeuner Str 5, D-09599 Freiberg, Germany

[2] TU Bergakad Freiberg, Inst Ceram Glass & Construct Mat, Agricolastr 17, D-09599 Freiberg, Germany

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2018年 / 743卷

关键词：

A; Intermetallics; C. heat capacity; Phase diagrams; Phase transitions; D; calorimetry; Thermal analysis; Thermodynamic modelling; CRYSTAL-STRUCTURE; HEAT-CAPACITY; THERMAL VACANCIES; X-RAY; PHASE; MODEL; EQUILIBRIA; REFINEMENT; ENTHALPY; FEAL2;

D O I：

10.1016/j.jallcom.2018.01.316

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The heat capacity of epsilon (Fe5Al8) was determined between 1395 and 1455 K by DSC measurements. The homogeneity ranges of the intermetallic phases zeta (FeAl2), eta (Fe2Al5) and theta (Fe4Al13) in the temperature range between 1073 and 1435 K were determined using WDS measurements on annealed and quenched samples in the composition range between 56.0 and 75.3 at.% Al. The solidus and liquidus temperatures of all samples were determined using DTA. A CALPHAD-type assessment of the Al-Fe system was done based on latest experimental results on heat capacity of the intermetallic phases. (c) 2018 Elsevier B.V. All rights reserved.

引用

页码：795 / 811

页数：17

共 48 条

[31]

PETRUSHE.MS, 1972, RUSS METALL+, P149

[32] Thermodynamic investigations in the Al-Fe system: Heat capacity measurements of three intermetallic phases [J].

Rank, Maximilian ;

Gotcu, Petronela ;

Franke, Peter ;

Seifert, Hans Juergen .

INTERMETALLICS, 2018, 94 :73-82

[33] *UBER DEN BINDUNGSZUSTAND BEI FE2AL5 UND MNAL6 [J].

SCHUBERT, K ;

KLUGE, M .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, 1953, 8 (11) :755-756

[34]

SCHUBERT K, 1953, NATURWISSENSCHAFTEN, V40, P437

[35]

Seierstein M., 1998, COST 507- THermochemical Database for Light Metal Alloys, V2, P34

[36] Determination of the crystal structure of the ε phase in the Fe-Al system by high-temperature neutron diffraction [J].

Stein, F. ;

Vogel, S. C. ;

Eumann, M. ;

Palm, M. .

INTERMETALLICS, 2010, 18 (01) :150-156

[37] Re-determination of transition temperatures in the Fe-Al system by differential thermal analysis [J].

Max-Planck-Institut für Eisenforschung GmbH, Düsseldorf, Germany ;

不详 .

Int. J. Mater. Res., 2007, 7 (580-588) :580-588

[38] A REGULAR SOLUTION MODEL FOR PHASES WITH SEVERAL COMPONENTS AND SUB-LATTICES, SUITABLE FOR COMPUTER-APPLICATIONS [J].

SUNDMAN, B ;

AGREN, J .

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1981, 42 (04) :297-301

[39] An assessment of the entire Al-Fe system including D03 ordering [J].

Sundman, Bo ;

Ohnuma, Ikuo ;

Dupin, Nathalie ;

Kattner, Ursula R. ;

Fries, Suzana G. .

ACTA MATERIALIA, 2009, 57 (10) :2896-2908

[40] EFFECT OF MAGNETIZATION ON L20 ORDERING REACTION IN IRON-ALUMINUM ALLOYS [J].

SWANN, PR ;

FISHER, RM .

APPLIED PHYSICS LETTERS, 1966, 9 (08) :279-&

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