Experimental investigation and thermodynamic assessment of the Al-Fe system

被引：37

作者：

Zienert, Tilo ^{[1
,2
]}

Fabrichnaya, Olga ^{[1
]}

机构：

[1] TU Bergakad Freiberg, Inst Mat Sci, Gustav Zeuner Str 5, D-09599 Freiberg, Germany

[2] TU Bergakad Freiberg, Inst Ceram Glass & Construct Mat, Agricolastr 17, D-09599 Freiberg, Germany

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2018年 / 743卷

关键词：

A; Intermetallics; C. heat capacity; Phase diagrams; Phase transitions; D; calorimetry; Thermal analysis; Thermodynamic modelling; CRYSTAL-STRUCTURE; HEAT-CAPACITY; THERMAL VACANCIES; X-RAY; PHASE; MODEL; EQUILIBRIA; REFINEMENT; ENTHALPY; FEAL2;

D O I：

10.1016/j.jallcom.2018.01.316

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The heat capacity of epsilon (Fe5Al8) was determined between 1395 and 1455 K by DSC measurements. The homogeneity ranges of the intermetallic phases zeta (FeAl2), eta (Fe2Al5) and theta (Fe4Al13) in the temperature range between 1073 and 1435 K were determined using WDS measurements on annealed and quenched samples in the composition range between 56.0 and 75.3 at.% Al. The solidus and liquidus temperatures of all samples were determined using DTA. A CALPHAD-type assessment of the Al-Fe system was done based on latest experimental results on heat capacity of the intermetallic phases. (c) 2018 Elsevier B.V. All rights reserved.

引用

页码：795 / 811

页数：17

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