Recent topics in dual hydrogen bonding catalysis

被引:47
作者
Nishikawa, Yasuhiro [1 ]
机构
[1] Meijo Univ, Fac Pharm, Tenpaku Ku, 150 Yagotoyama, Nagoya, Aichi 4688503, Japan
关键词
Hydrogen bonding; Thiourea; Squaramide; Anion binding; Dual catalysis; IONIC BRONSTED ACID; PICTET-SPENGLER REACTIONS; ANION-BINDING CATALYSIS; MICHAEL ADDITION; ASYMMETRIC ORGANOCATALYSIS; ENANTIOSELECTIVE ADDITION; SYNERGISTIC CATALYSIS; DONOR CATALYSTS; DESIGN; PHOTOREDOX;
D O I
10.1016/j.tetlet.2017.12.037
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Dual hydrogen bonding donors have received much attention in the area of organocatalysis after the discovery of chiral thiourea derivatives that act as asymmetric catalysts. This digest focuses on recent advances in this area categorized in the following three topics: 1) enhanced hydrogen bonding donor catalysis; new scaffolds with improved reactivity and selectivity are introduced and compared with established catalysts; 2) anion binding catalysis; recent advances in terms of catalysts and their applications is addressed; 3) multiple catalysis involving dual hydrogen bonding catalysts; a relatively new field of dual hydrogen bonding donor catalysis combined with other catalysis is introduced. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码:216 / 223
页数:8
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