Bio-inspired CO2 conversion by iron sulfide catalysts under sustainable conditions

被引：187
|
作者：
Roldan, A. [1 ]
Hollingsworth, N. [1 ]
Roffey, A. [1 ]
Islam, H. -U. [1 ,2 ]
Goodall, J. B. M. [1 ]
Catlow, C. R. A. [1 ]
Darr, J. A. [1 ]
Bras, W. [2 ]
Sankar, G. [1 ]
Holt, K. B. [1 ]
Hogarth, G. [1 ]
de Leeuw, N. H. [1 ]
机构：
[1] UCL, Dept Chem, London WC1H 0AJ, England
[2] European Synchrotron Radiat Facil, F-38043 Grenoble, France
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 35期
基金：
英国工程与自然科学研究理事会;
关键词：
CARBON-DIOXIDE; FORMIC-ACID; ORIGIN; REDUCTION; DECOMPOSITION; BIOCHEMISTRY; CHEMISTRY; MEMBRANE; FORMATE; REDOX;
D O I：
10.1039/c5cc02078f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The mineral greigite presents similar surface structures to the active sites found in many modern-day enzymes. We show that particles of greigite can reduce CO2 under ambient conditions into chemicals such as methanol, formic, acetic and pyruvic acid. Our results also lend support to the Origin of Life theory on alkaline hydrothermal vents.
引用
收藏
页码：7501 / 7504
页数：4
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