Rethinking the A cation in halide perovskites

被引：338
|
作者：
Lee, Jin-Wook [1 ,2 ]
Tan, Shaun [3 ,4 ]
Seok, Sang Il [5 ]
Yang, Yang [3 ,4 ]
Park, Nam-Gyu [6 ,7 ]
机构：
[1] Sungkyunkwan Univ, SKKU Adv Inst Nanotechnol SAINT, Suwon 16419, South Korea
[2] Sungkyunkwan Univ, Dept Nanoengn, Suwon 16419, South Korea
[3] Univ Calif Los Angeles, Dept Mat Sci & Engn, Los Angeles, CA 90095 USA
[4] Univ Calif Los Angeles, Calif NanoSyst Inst, Los Angeles, CA 90095 USA
[5] Ulsan Natl Inst Sci & Technol, Sch Energy & Chem Engn, Dept Energy Engn, Ulsan 44919, South Korea
[6] Sungkyunkwan Univ, Sch Chem Engn, Suwon 16419, South Korea
[7] Sungkyunkwan Univ, Ctr Antibonding Regulated Crystals, Suwon 16419, South Korea
来源：
SCIENCE | 2022年 / 375卷 / 6583期
基金：
新加坡国家研究基金会;
关键词：
SOLAR-CELLS; INORGANIC PEROVSKITES; TRANSPORTING MATERIAL; PHASE SEGREGATION; CARRIER LIFETIMES; HIGHLY EFFICIENT; CHARGE-CARRIERS; FORMAMIDINIUM; PERFORMANCE; STABILIZATION;
D O I：
10.1126/science.abj1186
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
The A cation in ABX(3) organic-inorganic lead halide perovskites (OLHPs) was conventionally believed to hardly affect their optoelectronic properties. However, more recent developments have unraveled the critical role of the A cation in the regulation of the physicochemical and optoelectronic properties of OLHPs. We review the important breakthroughs enabled by the versatility of the A cation and highlight potential opportunities and unanswered questions related to the A cation in OLHPs.
引用
收藏
页码：835 / +
页数：11
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