Rethinking the A cation in halide perovskites

被引：386

作者：

Lee, Jin-Wook ^{[1
,2
]}

Tan, Shaun ^{[3
,4
]}

Seok, Sang Il ^{[5
]}

Yang, Yang ^{[3
,4
]}

Park, Nam-Gyu ^{[6
,7
]}

机构：

[1] Sungkyunkwan Univ, SKKU Adv Inst Nanotechnol SAINT, Suwon 16419, South Korea

[2] Sungkyunkwan Univ, Dept Nanoengn, Suwon 16419, South Korea

[3] Univ Calif Los Angeles, Dept Mat Sci & Engn, Los Angeles, CA 90095 USA

[4] Univ Calif Los Angeles, Calif NanoSyst Inst, Los Angeles, CA 90095 USA

[5] Ulsan Natl Inst Sci & Technol, Sch Energy & Chem Engn, Dept Energy Engn, Ulsan 44919, South Korea

[6] Sungkyunkwan Univ, Sch Chem Engn, Suwon 16419, South Korea

[7] Sungkyunkwan Univ, Ctr Antibonding Regulated Crystals, Suwon 16419, South Korea

来源：

SCIENCE | 2022年 / 375卷 / 6583期

基金：

新加坡国家研究基金会;

关键词：

SOLAR-CELLS; INORGANIC PEROVSKITES; TRANSPORTING MATERIAL; PHASE SEGREGATION; CARRIER LIFETIMES; HIGHLY EFFICIENT; CHARGE-CARRIERS; FORMAMIDINIUM; PERFORMANCE; STABILIZATION;

D O I：

10.1126/science.abj1186

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

The A cation in ABX(3) organic-inorganic lead halide perovskites (OLHPs) was conventionally believed to hardly affect their optoelectronic properties. However, more recent developments have unraveled the critical role of the A cation in the regulation of the physicochemical and optoelectronic properties of OLHPs. We review the important breakthroughs enabled by the versatility of the A cation and highlight potential opportunities and unanswered questions related to the A cation in OLHPs.

引用

页码：835 / +

页数：11

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