Fluorescein-based fluorescent and colorimetric chemosensors for copper in aqueous media

被引：60

作者：

Abebe, Fasil A. ^{[1
]}

Sinn, Ekkehard ^{[1
]}

机构：

[1] Western Michigan Univ, Dept Chem, Kalamazoo, MI 49008 USA

来源：

TETRAHEDRON LETTERS | 2011年 / 52卷 / 41期

关键词：

Fluorescein; Fluorescence; Copper chemosensors; SELECTIVE FLUORESCENT; RHODAMINE; DERIVATIVES; SENSOR; CU(II); HG2+; SENSITIVITY; ION;

D O I：

10.1016/j.tetlet.2011.07.127

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two new fluorescein-based chemosensors for Cu(2+) were designed with highly selective "off-on" behavior, one of them working in both absorption and emission, the other only in absorption. Binding to Cu(2+) binding is reversible, as indicated by the bleaching of the color when the metal is extracted. The compounds form the basis for rapid, selective and sensitive Cu(2+) chemosensors in aqueous media. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：5234 / 5237

页数：4

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