Electronic transport and magnetic properties of a new nickel antimonide telluride, Ni2SbTe2

被引：24
|
作者：
Reynolds, TK [1 ]
Kelley, RF [1 ]
DiSalvo, FJ [1 ]
机构：
[1] Cornell Univ, Dept Chem & Chem Biol, Baker Lab, Ithaca, NY 14853 USA
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 2004年 / 366卷 / 1-2期
基金：
美国国家科学基金会;
关键词：
metals; chemical synthesis; crystal structure and symmetry; electronic transport; magnetic measurements;
D O I：
10.1016/j.jallcom.2003.07.008
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The mixed anion compound, Ni2SbTe2, has been prepared from the elements in a potassium iodide flux. The crystal structure is solved in the hexagonal space group P6(3)/mmc (no. 194) with lattice parameters a = b = 3.9030(9) Angstrom and c = 15.634(3) Angstrom. Sb and Te occupy crystallographically distinct anion sites within the crystal structure. The Seebeck coefficient, electrical resistivity, and magnetic susceptibility have been measured for the title compound, and shows typical metallic behavior. Extended Huckel band structure calculations also predict metallic behavior in bands dominated by Ni and Te orbital contributions. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码：136 / 144
页数：9
相关论文
共 50 条
  • [1] Synergic Effect in a New Electrocatalyst Ni2SbTe2 for Oxygen Reduction Reaction
    Li, Li-Heng
    Yuan, Jun-Hui
    Xue, Kan-Hao
    Xu, Meng
    Xu, Ming
    Wang, Jia-Fu
    Miao, Xiang-Shui
    JOURNAL OF PHYSICAL CHEMISTRY C, 2020, 124 (06): : 3671 - 3680
  • [2] Vavrinite Ni2SbTe2, a new mineral species from the kunratice Cu-Ni sulfide deposit, Czech Republic
    Laufek, Frantisek
    Drabek, Milan
    Skala, Roman
    Haloda, Jakub
    Taborsky, Zdenek
    Cisarova, Ivana
    CANADIAN MINERALOGIST, 2007, 45 : 1213 - 1219
  • [3] Realizing Efficient Catalytic Performance and High Selectivity for Oxygen Reduction Reaction on a 2D Ni2SbTe2 Monolayer
    Zhao, Lusi
    Yu, Guangtao
    Huang, Xuri
    Chen, Wei
    INORGANIC CHEMISTRY, 2022, 61 (04) : 2284 - 2291
  • [4] Synthesis and properties of a new metal-rich nickel antimonide telluride or selenide:: Ni7-δSbX2 (δ ≈ 1.3;: X = Se or Te)
    Reynolds, TK
    Bales, JG
    DiSalvo, FJ
    CHEMISTRY OF MATERIALS, 2002, 14 (11) : 4746 - 4751
  • [5] A substitution of nickel by antimony:: Crystal and electronic structure of the new antimonide Hf6Ni1-xSb2+x
    Kleinke, H
    JOURNAL OF ALLOYS AND COMPOUNDS, 1998, 270 (1-2) : 136 - 141
  • [6] Electronic Transport and Magnetic Properties of Co/SiO2 Magnetic Nanocomposites
    Radchenko, Mykhailo
    Lashkarev, Georgii
    Baibara, Oleksii
    Bugaiova, Maryna
    Stelmakh, Yaroslav
    Krushynska, Larysa
    Foltyn, Marek
    Knoff, Wojciech
    Story, Tomasz
    Nedelko, Natalia
    Slawska-Waniewska, Anna
    PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2019, 256 (11):
  • [7] Electronic and magnetic properties and their response to pressure in Ni2MnB
    Pugaczowa-Michalska, Maria
    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2008, 320 (16) : 2083 - 2088
  • [8] Electronic and Magnetic Properties of Ni2-xPtxMnGa Cubic Alloys
    Boularaf, A.
    Drief, F.
    Zaoui, A.
    Kacimi, S.
    PHYSICS OF THE SOLID STATE, 2024, 66 (12) : 625 - 633
  • [9] Magnetic and electronic properties of Fe and Ni codoped SnO2
    Okabayashi, Jun
    Kono, Shin
    Yamada, Yasuhiro
    Nomura, Kiyoshi
    JOURNAL OF APPLIED PHYSICS, 2012, 112 (07)
  • [10] Investigation of magnetic and electrical transport properties of Dy2Ni2Sn
    Karmakar, S. K.
    Giri, S.
    Majumdar, S.
    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2014, 370 : 96 - 99
12345