An alternative route to highly luminescent platinum(II) complexes:: Cyclometalation with N∧C∧N-coordinating dipyridylbenzene ligands

被引:346
作者
Williams, JAG
Beeby, A
Davies, ES
Weinstein, JA
Wilson, C
机构
[1] Univ Durham, Dept Chem, Durham DH1 3LE, England
[2] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
关键词
D O I
10.1021/ic035083+
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The remarkable luminescence properties of the platinum(II) complex of 1, 3-di (2-pyridyl) benzene, acting as a terdentate NCN-coordinating ligand cyclometalated at C2 of the benzene ring ([PtL1-Cl]), have been investigated, together with those of two new 5-substituted analogues [(PtLCl)-Cl-2] and [(PtLCl)-Cl-3] {HL2 = methyl-3,5-di(2-pyridyl)benzoate; HL3 = 3,5-di(2-pyridyl)toluenel. All three complexes are intense emitters in degassed solution at 298 K (lambdamax 480-580 nm; phi(lum), = 0.60, 0.58, and 0.68 in CH2Cl2), displaying highly structured emission spectra in dilute solution, with lifetimes in the microsecond range (7.2, 8.0, and 7.8,us). On the basis of the very small Stokes shift, the highly structured profiles, and the relatively long lifetimes, the emission is attributed to an excited state of primarly 3pi-pi* character. At concentrations >1 X 10(-5) M, structureless excimer emission centered at ca. 700 nm is observed. The X-ray crystal structure of [PtL Cl-2] is also reported.
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页码:8609 / 8611
页数:3
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