High Sensitive Surface Plasmon Resonance (SPR) Sensor Based on Modified Calix(4)arene Self Assembled Monolayer for Cadmium Ions Detection

被引：21

作者：

Benounis, M. ^{[1
]}

Jaffrezic, N. ^{[2
]}

Martelet, C. ^{[3
]}

Dumazet-Bonnamour, I. ^{[4
]}

Lamartine, R. ^{[4
]}

机构：

[1] Univ Khenchela, Lab Sensors Instrumentat & Proc LCIP, Inst Sci & Technol, Khenchela 40000, Algeria

[2] Univ Claude Bernard Lyon 1, LSA, F-69622 Villeurbanne, France

[3] Ecole Cent Lyon, CEGELY, UMR CNRS 5005, F-69134 Ecully, France

[4] Univ Claude Bernard Lyon 1, LACE, F-69622 Villeurbanne, France

来源：

MATERIALS TRANSACTIONS | 2015年 / 56卷 / 04期

关键词：

calixarene; self assembled monolayer (SAM); SPR sensors; cadmium ions; heavy metals; sensitivity; GOLD ELECTRODE; SUPRAMOLECULAR CHEMISTRY; HORSERADISH-PEROXIDASE; WATER SAMPLES; HEAVY-METALS; ICP-MS; LEAD; IMMOBILIZATION; RECOGNITION; MERCURY;

D O I：

10.2320/matertrans.M2014366

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

In this work, a new chromogenic calix(4) arene was functionalized onto self assembled monolayer (SAM) of cysteamine for cadmium ions detection and tested by using SPR measurement. The functionalization of modified SPR sensor is based on the oxidation of calixarene-SAM alcohol group to quinone. Four interfering ions were used Cu2+, Co2+, Mg2+ and Ca2+. pH of sensor in which the sensitivity of sensor is higher was optimized for cadmium ions and detection of ions was made in basic solution. Detection limit reached for Cd2+ is lower than 10(-11) M with a dynamic response time of about 16 s when changing from 10(-6) M cadmium to 10(-5) M.

引用

页码：539 / 544

页数：6

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