Metal chalcogenide frameworks - A Rare (3,4)-connected chalcogenide superlattice and its photoelectric effect

被引：116

作者：

Zhang, Qichun ^{[1
]}

Liu, Yang ^{[1
]}

Bu, Xianhui ^{[2
]}

Wu, Tao ^{[1
]}

Feng, Pingyun ^{[1
]}

机构：

[1] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA

[2] Calif State Univ Long Beach, Dept Chem & Biochem, Long Beach, CA 90840 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 01期

关键词：

cadmium; cluster compounds; hydrothermal synthesis; S ligands; semiconductors;

D O I：

10.1002/anie.200703442

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Graph Presented) Light switch: A photoelectric chalcogenide with a (3,4)-connected open-framework structure based on large Cd-S-SAr clusters with boracite-type topology has been synthesized. Its structure (depicted: Cd green, S yellow; Ar omitted) and optical properties have been characterized. The superlattice reproducibly generates a transient photocurrent on excitation by visible light (see picture). SAr = 3-methylbenzenethiolate. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：113 / 116

页数：4