Advanced electrochemical analysis of metal-ion battery materials for rationalizing and improving battery performance

被引：10

作者：

Nikitina, Victoria A. ^{[1
]}

机构：

[1] Skolkovo Inst Sci & Technol, Ctr Energy Sci & Technol, Nobel Str 3, Moscow 121205, Russia

来源：

CURRENT OPINION IN ELECTROCHEMISTRY | 2021年 / 29卷 / 29期

关键词：

Intercalation kinetics; Electrochemical methods; Solid electrolyte inter-phase; Phase transformation; Rate-limitations; SINGLE-PARTICLE ELECTRODE; KINETICS; LIFEPO4; INTERCALATION; TRANSPORT; SEI; LITHIATION; INTERFACE; IMPEDANCE; INSERTION;

D O I：

10.1016/j.coelec.2021.100768

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Rate performance of metal-ion batteries is determined by the kinetics of diffusive and charge transfer processes in composite electrodes, which can be quantitatively described using various experimental and modeling approaches. Advanced electrochemical methods and experimental techniques allow differentiating between various contributions to the over potential and capacity fading at the individual particle, composite electrode and full cell levels. Apart from the practical significance for battery performance optimization, electrochemical kinetic studies provide a deeper understanding of intercalation mechanisms, including ionic transport through interfacial layers and the patterns of phase boundary propagation in phase-transforming particles.

引用

页数：7

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