Reductant composition influences the coordination of atomically dispersed Rh on anatase TiO2

被引：44

作者：

Asokan, Chithra ^{[1
]}

Ho Viet Thang ^{[2
,3
]}

Pacchioni, Gianfranco ^{[2
]}

Christopher, Phillip ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Dept Chem Engn, Santa Barbara, CA 93106 USA

[2] Univ Milano Bicocca, Dipartimento Sci Mat, Via Cozzi 55, I-20125 Milan, Italy

[3] Univ Da Nang, Univ Sci & Technol, 54 Nguyen Luong Bang, Danang 550000, Vietnam

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2020年 / 10卷 / 06期

关键词：

SURFACE HYDROXYL-GROUPS; STABLE SINGLE-ATOM; CARBON-MONOXIDE; CO; RHODIUM; CHEMISORPTION; AL2O3; OXIDE; ADSORPTION; REACTIVITY;

D O I：

10.1039/d0cy00146e

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Atomically dispersed noble metal catalysts have received recent interest, although the coordination of the metal to the support and how this is influenced by pre-treatment have not often been elucidated. We combine CO FTIR-TPD and DFT to distinguish how catalyst reduction via CO or H-2 influence the local metal coordination and molecular desorption processes.

引用

页码：1597 / 1601

页数：5

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