A new two-dimensional AgI coordination polymer with Ag•••C interactions:: Thermal, fluorescence, structural and solution studies

被引：30

作者：

Akhbari, Kamran ^{[1
]}

Morsali, Ali ^{[1
]}

Rafiei, Shahnaz ^{[2
]}

Zeller, Matthias ^{[3
]}

机构：

[1] Tarbiat Modares Univ, Sch Sci, Dept Chem, Tehran, Iran

[2] Imam Khomeini Int Univ, Fac Sci, Dept Chem, Qazvin, Iran

[3] Youngstown State Univ, Dept Chem, Youngstown, OH 44555 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2008年 / 693卷 / 02期

基金：

美国国家科学基金会;

关键词：

silver(I); toluene-4-sulfonic acid; Ag center dot center dot center dot C interaction; coordination polymer; fluorescence; thermal; solution study;

D O I：

10.1016/j.jorganchem.2007.10.057

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A 2D polymer with Ag center dot center dot center dot C interactions, [Ag(mu(5)-TS)](n) (1) [TS- = toluene-4-sulfonate], has been synthesized and characterized and its structure was determined by X-ray crystallography. In addition to coordination of the 0 atoms of TS-, the Ag atoms also form weak eta(l) Ag center dot center dot center dot C interactions. The thermal stability of 1 was studied by thermal gravimetric (TG) and differential thermal analyses (DTA). The ligand and compound 1 are luminescent in DMF, with emission maxima at 358 and 335, respectively. Solution studies of complex 1 were done in DMF and in CH3CN. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：257 / 262

页数：6

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