Polyaniline - rare earth metal chloride composites as an adsorbent cum electrode material for supercapacitor performance investigation

被引:11
作者
Dominic, J. [1 ]
Karthikeyan, M. [2 ]
Kumar, K. K. Satheesh [1 ]
机构
[1] Gandhigram Rural Inst Deemed Univ, Dept Chem, Gandhigram 624302, TN, India
[2] Kongu Engn Coll, Ctr Environm Res, Erode 638060, TN, India
关键词
Polyaniline-rare earth metal composites; Removal of fluoride; Adsorption; Solid waste; Supercapacitor; VOLUMETRIC CAPACITIVE PERFORMANCE; DOPED POLYANILINE; FLUORIDE REMOVAL; ADSORPTION; POLYMER; WATER; WASTE; FABRICATION; HYDROXIDE; IONS;
D O I
10.1016/j.est.2022.103971
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Polyaniline - rare earth metal chloride composites are synthesized and used to remove fluoride ions from drinking water as part of a "prospective strategy to sustainable waste management". The influence of variables such as the effect of initial fluoride concentrations, pH, contact time, effects of co-ions, and temperature on the removal of fluoride ions have been examined. The thermodynamic studies showed that the reaction is endothermic, and the reaction is favoured at an elevated temperature. The reaction mechanism is explored with an analysis of Fourier Transform-Infrared spectroscopy, X-Ray diffraction technique, Scanning electron microscopy, Energy Dispersive X-Ray Analysis and X-ray photoelectron spectroscopy during the adsorption of fluoride ions. The solid waste material generated after defluoridation is utilized as an electrode material for supercapacitor performance study through "Waste utilization for technology."
引用
收藏
页数:16
相关论文
共 82 条
[61]   Characterization of highly conducting lithium salt doped polyaniline films prepared from polymer solution [J].
Ryu, KS ;
Moon, BW ;
Joo, J ;
Chang, SH .
POLYMER, 2001, 42 (23) :9355-9360
[62]   ARSENIC AND FLUORIDE REMOVAL FROM GROUNDWATER BY REVERSE-OSMOSIS [J].
SCHNEITER, RW ;
MIDDLEBROOKS, EJ .
ENVIRONMENT INTERNATIONAL, 1983, 9 (04) :289-291
[63]   The effect of substrate temperature on the oxidation behavior of erbium thick films [J].
Shen, H. H. ;
Peng, S. M. ;
Long, X. G. ;
Zhou, X. S. ;
Yang, L. ;
Zu, X. T. .
VACUUM, 2012, 86 (08) :1097-1101
[64]   Spectroelectrochemical investigations of soluble polyaniline synthesized via new inverse emulsion pathway [J].
Shreepathi, S ;
Holze, R .
CHEMISTRY OF MATERIALS, 2005, 17 (16) :4078-4085
[65]   TRACE-ELEMENT REMOVAL FROM ASH DAM WATERS BY NANOFILTRATION AND DIFFUSION DIALYSIS [J].
SIMONS, R .
DESALINATION, 1993, 89 (03) :325-341
[66]   Conducting Polyaniline Nanowire and Its Applications in Chemiresistive Sensing [J].
Song, Edward ;
Choi, Jin-Woo .
NANOMATERIALS, 2013, 3 (03) :498-523
[67]   Fluoride adsorption onto granular ferric hydroxide: Effects of ionic strength, pH, surface loading, and major co-existing anions [J].
Tang, Yulin ;
Guan, Xiaohong ;
Wang, Jianmin ;
Gao, Naiyun ;
McPhail, Martin R. ;
Chusuei, Charles C. .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 171 (1-3) :774-779
[68]   X-ray photoelectron spectroscopy analysis for the chemical impact of solvent addition rate on electromagnetic shielding effectiveness of HCl-doped polyaniline nanopowders [J].
Tantawy, Hesham Ramzy ;
Kengne, Blaise-Alexis F. ;
McIlroy, David N. ;
Nguyen, Tai ;
Heo, Deukhyoun ;
Qiang, You ;
Aston, D. Eric .
JOURNAL OF APPLIED PHYSICS, 2015, 118 (17)
[69]  
Tererin Y.A., 2002, Russ. Chem. Rev, V71, P347, DOI DOI 10.1070/RC2002V071N05ABEH000717
[70]   Synthesis, Structural, Magnetic and XPS Studies of Garnet Type-Dysprosium Iron Oxides by Glycine-Assisted Combustion Method [J].
Tholkappiyan, R. ;
Vishista, K. .
NANOSCIENCE AND NANOTECHNOLOGY LETTERS, 2015, 7 (06) :469-475