A unique ZnFe2O4/graphene nanoplatelets nanocomposite for electrochemical energy storage and efficient visible light driven catalysis for the degradation of organic noxious in wastewater

被引:48
作者
Israr, M. [1 ,2 ]
Iqbal, Javed [1 ]
Arshad, Aqsa [3 ]
Aisida, Samson O. [1 ,4 ,5 ]
Ahmad, Ishaq [5 ,6 ]
机构
[1] Quaid I Azam Univ, Dept Phys, LNT, Islamabad, Pakistan
[2] Autonomous Univ Barcelona, Catalan Inst Nanosci & Nanotechnol, Barcelona, Spain
[3] Int Islamic Univ, Dept Phys, Islamabad, Pakistan
[4] Univ Nigeria, Dept Phys & Astron, Nsukka, Nigeria
[5] Quaid I Azam Univ, Natl Ctr Phys, Islamabad, Pakistan
[6] Northwestern Polytech Univ, NPU NCP Joint Int Res Ctr Adv Nanomat & Defects E, Xian 710072, Peoples R China
关键词
Nanocomposites; Electrochemical properties; Photocatalysis; Graphene nanoplatelets; Zn ferrite; ENHANCED PHOTOCATALYTIC PERFORMANCE; NITROGEN-DOPED CARBON; HIGHLY EFFICIENT; OXIDE NANOCOMPOSITES; FACILE SYNTHESIS; THIN-FILM; GRAPHENE; COMPOSITE; ADSORPTION; NANOSHEETS;
D O I
10.1016/j.jpcs.2020.109333
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A series of ZnFe2O4/graphene nanoplatelets ((ZF)(1-x)(GNPs)(x)) nanocomposites have been synthesized and characterized. By optimizing the weight ratio of graphene nanoplatelets (GNPs), the synthesized nanocomposites have been identified as an excellent material for electrochemical capacitors with outstanding electrochemical capacitance (314 Fg(-1) at 0.5 Ag-1), high rate performance, and long-standing cyclic stability (77.6% retention). The enhanced electrochemical performance might be adduced to the improved electrode/electrolyte charge transfer interface and conducting nature of GNPs. Besides, (ZF)(1-x)(GNPs)(x) nanocomposites exhibit outstanding visible light driven photocatalytic efficiency for the removal of methylene blue (MB) dye in water i.e., 97.46% of the MB is degraded in 70 min, which can be primarily ascribed to the enhanced photo Fenton reaction, effective electron-hole (e(-)/h(+)) separation and strong interfacial coupling between ZnFe2O4 nanoparticles (ZF NPs) and GNPs. Our results offer new insights into multifunctional nanocomposites for the electrochemical energy storage and treatment of polluted wastewater.
引用
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页数:9
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