Rational design, synthesis and crystal structure investigation of hydrogen-bonded coordination polymers of bicyclic bis-lactam dicarboxylates

被引:9
作者
Lenev, DA
Lyssenko, KA
Kostyanovsky, RG
机构
[1] Russian Acad Sci, NN Semenov Chem Phys Inst, Moscow 119991, Russia
[2] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
关键词
carboxylate ligands; chirality; crystal engineering; hydrogen bonding; lactams;
D O I
10.1002/ejic.200300115
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The crystal structures of the racemic coordination polymers (+/-)-1 to (+/-)-4 and the coordination dimers (+/-)-6 and (+/-)-7, containing molecular "brick walls" with inorganic coatings and molecular "brick walls" with mixed organic-inorganic coatings, respectively, were predicted and verified on the basis of the zigzag R-2(2)(8) H-bonded tape columnar packing motif of the purely organic racemic dialkyl 3,6-dioxo-2,5-diazabicyclo[2.2.2]octane-1,4-dicarboxylates. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.
引用
收藏
页码:2979 / 2985
页数:7
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