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Recent Advances on Electrolysis for Simultaneous Generation of Valuable Chemicals at both Anode and Cathode
被引:176
|作者:
Li, Rui
[1
]
Xiang, Kun
[2
]
Peng, Zhikun
[1
]
Zou, Yuqin
[3
]
Wang, Shuangyin
[3
]
机构:
[1] Zhengzhou Univ, Henan Inst Adv Technol, Zhengzhou 450003, Peoples R China
[2] Shenzhen Univ, Coll Mat Sci & Engn, Shenzhen 518060, Peoples R China
[3] Hunan Univ, Natl Supercomp Ctr Changsha, Coll Chem & Chem Engn,Prov Hunan Key Lab Graphene, Adv Catalyt Engn Res Ctr,Minist Educ,State Key La, Changsha 410082, Peoples R China
基金:
中国国家自然科学基金;
中国博士后科学基金;
关键词:
co-electrolysis;
electrocatalytic oxidation;
electrocatalytic reduction;
integrating reaction;
valuable chemicals;
ELECTROCATALYTIC NITROGEN REDUCTION;
VALUE-ADDED CHEMICALS;
CARBON-DIOXIDE;
SELECTIVE ELECTROOXIDATION;
HYDROGEN GENERATION;
ELECTROCHEMICAL COPRODUCTION;
GLYCEROL ELECTROOXIDATION;
ALKALINE-MEDIUM;
OXIDATION;
CONVERSION;
D O I:
10.1002/aenm.202102292
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
To make efficient use of electrical energy in the whole electrocatalysis conversion process, the integrating of anode and cathode reactions plays a vital role. The combination of electrocatalytic anodic oxidation with cathodic reduction can not only maximize the return of energy investment, but also produces value-added materials on both sides. Herein, in this review, recent advances in co-electrolysis processes for valuable chemical production are systematically summarized. To be more specific, the popular hydrogen evolution reaction, carbon dioxide reduction reaction, nitrogen reduction reaction as well as nitrate reduction reaction integrated with anodic oxidation reactions to value-added products, respectively are comprehensively reviewed, and then other paired electrolysis systems (especially for biomass-based compounds) toward high-value-added chemical generation are discussed in detail. This review sheds light on the integration of electrocatalytic reductions and oxidation reactions to develop high-value substances. To benefit researchers and facilitate the progress in this field, the challenges and future prospects for these integrated reactions are also proposed.
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