Combining N,S-Codoped C and CeO2: A Unique Hinge-like Structure for Efficient Photocatalytic Hydrogen Evolution

被引：42

作者：

Hao, Juan ^{[1
]}

Zhan, Wenwen ^{[1
]}

Sun, Liming ^{[1
]}

Zhuang, Guilin ^{[2
]}

Wang, Xiaojun ^{[1
]}

Han, Xiguang ^{[1
]}

机构：

[1] Jiangsu Normal Univ, Sch Chem & Chem Engn, Dept Chem, Jiangsu Key Lab Green Synthet Chem Funct Mat, Xuzhou 221116, Jiangsu, Peoples R China

[2] Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310014, Peoples R China

来源：

INORGANIC CHEMISTRY | 2020年 / 59卷 / 01期

基金：

中国国家自然科学基金;

关键词：

H-2; EVOLUTION; OXIDE; NANOPARTICLES; SHELL; DEGRADATION; PERFORMANCE; REACTIVITY; NANOSHEETS; COMPOSITE; CATALYSTS;

D O I：

10.1021/acs.inorgchem.9b03204

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

N- and S-doped C-encapsulated CeO2 with a hinge-like nanostructure (CeO2@N,S-C HN) has been obtained by using a Ce-based metal-organic framework (Ce-MOF-808) as a precursor. Due to the synergistic effects of its special structure and N,S-doped C layer, CeO2@N,S-C HN exhibits high activity of photocatalytic hydrogen (H-2) evolution. Density functional calculations are used to obtain a fundamental understanding of the high H-2 production rate of CeO2@N,S-C HN.

引用

页码：937 / 942

页数：6

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