Alchemilla Vulgaris Extract as Green Inhibitor of Copper Corrosion in Hydrochloric Acid

被引:26
作者
Ahmed, Rasha Khalid [1 ,2 ]
Zhang, Shengtao [1 ]
机构
[1] Chongqing Univ, Sch Chem & Chem Engn, Chongqing, Peoples R China
[2] Univ Tikrit, Coll Engn, Dept Chem Engn, Tikrit, Iraq
基金
中国国家自然科学基金;
关键词
Copper; Corrosion inhibitors; ALV extract; Eco-friendly; Hydrochloric acid; MILD-STEEL; SULFURIC-ACID; 3.5-PERCENT NACL; PERFORMANCE; DERIVATIVES; CU;
D O I
10.20964/2019.11.43
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
This paper aims to assess the anti-corrosion capability of Alchemilla Vulgaris (ALV) extract in 1 M HCl on pure copper with the perspective of exploring and developing an eco-friendly or natural corrosion inhibitor. Therefore, in the current study, the extraction of ALV was made from its leaves and its anticorrosion potential was studied by utilizing weight loss experiment, potentiodynamic polarization test, scanning electron microscopy (SEM) analysis and electrochemical impedance spectroscopy (EIS). It has been found that in 1 M HCl solution, the ALV was effectively inhibited the corrosion on pure copper metal. The results obtained from the electrochemical tests and weight loss way proved that the anti-corrosion capability of ALV was increased with increasing its concentration. Inhibition is achieved through the adsorption of Alchemilla molecules onto the pure copper surface by adopting the Langmuir adsorption isotherm model. SEM study also indicates that the inhibitor gave positive results when adsorption on the surface of copper. This study directs attention to highly inhibitive properties of some natural compounds as the ALV extract. Hence, it is considered the first time to investigate the efficiency of ALV extract as a potential pure copper corrosion inhibitor in a 1M HCl solution. The anti-corrosion effect of ALV extract has been proven by standard methods. The findings of this research are important because ALV, as a natural inhibitor material, could find use in industries where pure Cu is used.
引用
收藏
页码:10657 / 10669
页数:13
相关论文
共 51 条
[1]   Corrosion Inhibition Effect of some Pyridopyrimidine Derivatives for Carbon Steel in 0.5 M HCl Solution [J].
Al-Nami, Samar Y. .
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2019, 14 (04) :3986-4002
[2]  
ALQUDAH MA, 2011, J CHEM, V8, P326
[3]  
Antonijevic MM, 2008, INT J ELECTROCHEM SC, V3, P1
[4]   Electrochemical behaviour of Cu24Zn5Al alloy in alkaline medium in the presence of chloride ions and benzotriazole [J].
Antonijevic, M. M. ;
Milic, S. M. .
MATERIALS CHEMISTRY AND PHYSICS, 2009, 118 (2-3) :385-391
[5]   Films formed on copper surface in chloride media in the presence of azoles [J].
Antonijevic, Milan M. ;
Milic, Snezana M. ;
Petrovic, Marija B. .
CORROSION SCIENCE, 2009, 51 (06) :1228-1237
[6]  
Ben H., 2012, INT J ELECTROCHEM SC, V7, P2361
[8]  
Bourazmi H., 2018, J. Mater. Environ. Sci., V9, P1058, DOI [10.26872/jmes.2017.9.3.118, DOI 10.26872/JMES.2017.9.3.118]
[9]   Environmentally benign green inhibitor to attenuate acid corrosion of 6061Aluminum-15%(v) SiC(P) composite [J].
Charitha, B. P. ;
Rao, Padmalatha .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2018, 58 :357-368
[10]   Effect of 1-(3-phenoxypropyl) pyridazin-1-ium bromide on steel corrosion inhibition in acidic medium [J].
El-Hajjaji, F. ;
Messali, M. ;
Martinez de Yuso, M. V. ;
Rodriguez-Castellon, E. ;
Almutairi, S. ;
Bandosz, Teresa J. ;
Algarra, M. .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2019, 541 :418-424