Micro- and nano-sized bentonite filled composite superabsorbents of chitosan and acrylic copolymer for removal of synthetic dyes from water

被引:56
作者
Bhattacharyya, Ruma [1 ]
Ray, Samit Kumar [1 ]
机构
[1] Univ Calcutta, Dept Polymer Sci & Technol, Kolkata 700009, India
关键词
Chitosan; Copolymer; Bentonite; Dye; Isotherms; Kinetics; AQUEOUS-SOLUTION; METHYLENE-BLUE; CATIONIC DYES; SWELLING BEHAVIOR; MALACHITE GREEN; ADSORPTION; HYDROGELS; KINETICS; NETWORK; ACID);
D O I
10.1016/j.clay.2014.09.015
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Bentonite clay, chitosan and acrylic copolymer gels have been separately reported for the adsorption of dyes. In the present work these three kinds of adsorbents were combined to make composite hydrogels. The hydrogels were characterized by FTIR, XRD, DTA-TGA and SEM. The swelling, diffusion and network parameters of the hydrogels were also evaluated. These composite hydrogels were used for the removal of malachite green and methyl violet dyes from water. The composite hydrogels showed high adsorption and removal% of both of these dyes. The mass transfer coefficient diffusion coefficient and thermodynamic parameters of the dye adsorption were also determined. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:510 / 520
页数:11
相关论文
共 42 条
[1]   Chitosan-clay composite as highly effective and low-cost adsorbent for batch and fixed-bed adsorption of methylene blue [J].
Auta, M. ;
Hameed, B. H. .
CHEMICAL ENGINEERING JOURNAL, 2014, 237 :352-361
[2]   Microbial decolorization of textile-dye-containing effluents: A review [J].
Banat, IM ;
Nigam, P ;
Singh, D ;
Marchant, R .
BIORESOURCE TECHNOLOGY, 1996, 58 (03) :217-227
[3]   Adsorption kinetics and thermodynamic parameters of cationic dyes from aqueous solutions by using a new strong cation-exchange resin [J].
Bayramoglu, Gulay ;
Altintas, Begum ;
Arica, M. Yakup .
CHEMICAL ENGINEERING JOURNAL, 2009, 152 (2-3) :339-346
[4]  
Bhattacharyya R., 2013, J IND ENG CHEM, V106, P109
[5]   Superabsorbent hydrogels based on cellulose for smart swelling and controllable delivery [J].
Chang, Chunyu ;
Duan, Bo ;
Cai, Jie ;
Zhang, Lina .
EUROPEAN POLYMER JOURNAL, 2010, 46 (01) :92-100
[6]   Adsorption of tannic acid, humic acid, and dyes from water using the composite of chitosan and activated clay [J].
Chang, MY ;
Juang, RS .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2004, 278 (01) :18-25
[7]   Sorption kinetics for the removal of copper and zinc from effluents using bone char [J].
Cheung, CW ;
Porter, JF ;
McKay, G .
SEPARATION AND PURIFICATION TECHNOLOGY, 2000, 19 (1-2) :55-64
[8]   Morphology and gas transport properties of acrylic resin/bentonite nanocomposite coatings [J].
Choudalakis, G. ;
Gotsis, A. D. .
PROGRESS IN ORGANIC COATINGS, 2014, 77 (04) :845-852
[9]   Non-conventional low-cost adsorbents for dye removal: A review [J].
Crini, G .
BIORESOURCE TECHNOLOGY, 2006, 97 (09) :1061-1085
[10]   Simple method for preparation of chitosan/poly(acrylic acid) blending hydrogel beads and adsorption of copper(II) from aqueous solutions [J].
Dai, Jie ;
Yan, Han ;
Yang, Hu ;
Cheng, Rongshi .
CHEMICAL ENGINEERING JOURNAL, 2010, 165 (01) :240-249