High yield synthesis of a neutral and carbonyl-rich terminal arylborylene complex

被引：36
作者：
Braunschweig, Holger [1 ]
Ye, Qing [1 ]
Radacki, Krzysztof [1 ]
机构：
[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 21期
基金：
欧洲研究理事会;
关键词：
TRANSITION-METAL-COMPLEXES; LIGANDS ER E; BORYLENE TRANSFER; THERMAL CONDITIONS; B-TL; IRON; COORDINATION; MONONUCLEAR; REACTIVITY; FUNCTIONALIZATION;
D O I：
10.1039/c2cc17445f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
High yield synthesis of trans-[(Me3P)(OC)(3)Fe = BDur] (Dur, "Duryl" = 2,3,4,6-Me4C6H) is achieved by salt elimination and subsequent liberation of trimethylsilylbromide from K[Fe(CO)(3)(PMe3)SiMe3] and Br(2)BDur.
引用
收藏
页码：2701 / 2703
页数：3
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