High yield synthesis of a neutral and carbonyl-rich terminal arylborylene complex

被引：36
作者：
Braunschweig, Holger [1 ]
Ye, Qing [1 ]
Radacki, Krzysztof [1 ]
机构：
[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 21期
基金：
欧洲研究理事会;
关键词：
TRANSITION-METAL-COMPLEXES; LIGANDS ER E; BORYLENE TRANSFER; THERMAL CONDITIONS; B-TL; IRON; COORDINATION; MONONUCLEAR; REACTIVITY; FUNCTIONALIZATION;
D O I：
10.1039/c2cc17445f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
High yield synthesis of trans-[(Me3P)(OC)(3)Fe = BDur] (Dur, "Duryl" = 2,3,4,6-Me4C6H) is achieved by salt elimination and subsequent liberation of trimethylsilylbromide from K[Fe(CO)(3)(PMe3)SiMe3] and Br(2)BDur.
引用
收藏
页码：2701 / 2703
页数：3
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共 53 条
  • [1] A terminal borylene ruthenium complex: From B-H activation to reversible hydrogen release
    Alcaraz, Gilles
    Helmstedt, Ulrike
    Clot, Eric
    Vendier, Laure
    Sabo-Etienne, Sylviane
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (39) : 12878 - +
  • [2] Bis σ-Bond Dihydrogen and Borane Ruthenium Complexes: Bonding Nature, Catalytic Applications, and Reversible Hydrogen Release
    Alcaraz, Gilles
    Grellier, Mary
    Sabo-Etienne, Sylviane
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (10) : 1640 - 1649
  • [3] Cationic terminal borylene complexes: Structure/bonding analysis and [4+1] cycloaddition reactivity of a BN vinylidene analogue
    Aldridge, Simon
    Jones, Cameron
    Gans-Eichler, Timo
    Stasch, Andreas
    Kays , Deborah L.
    Coombs, Natalie D.
    Willock, David J.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (37) : 6118 - 6122
  • [4] Borylene Transfer from Transition Metal Borylene Complexes
    Anderson, Carly E.
    Braunschweig, Holger
    Dewhurst, Rian D.
    [J]. ORGANOMETALLICS, 2008, 27 (24) : 6381 - 6389
  • [5] Group VI metal aminoborylene complex-catalyzed demercuration reactions of bis(alkynyl)mercurials
    Apostolico, Leonardo
    Braunschweig, Holger
    Crawford, Andrew G.
    Herbst, Thomas
    Rais, Daniela
    [J]. CHEMICAL COMMUNICATIONS, 2008, (04) : 497 - 498
  • [6] PREPARATION AND CHARACTERIZATION BY P-31-NMR SPECTROSCOPY OF MIXED DISUBSTITUTED [FE(CO)3LL'] COMPLEXES
    BELLACHIOMA, G
    CARDACI, G
    MACCHIONI, A
    REICHENBACH, G
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 391 (03) : 367 - 376
  • [7] Towards Homoleptic Borylene Complexes: Incorporation of Two Borylene Ligands into a Mononuclear Iridium Species
    Bertsch, Stefanie
    Braunschweig, Holger
    Christ, Bastian
    Forster, Melanie
    Schwab, Katrin
    Radacki, Krzysztof
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (49) : 9517 - 9520
  • [8] Aminoborylene complexes of group 6 elements and iron: A synthetic, structural, and quantum chemical study
    Blank, Benoit
    Colling-Hendelkens, Miriam
    Kollann, Carsten
    Radacki, Krzysztof
    Rais, Daniela
    Uttinger, Katharina
    Whittell, George R.
    Braunschweig, Holger
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (17) : 4770 - 4781
  • [9] Chemical bonding in mononuclear transition metal complexes with Group 13 diyl ligands ER (E = B-Tl) Part X: Theoretical studies of inorganic compounds
    Boehme, C
    Uddin, J
    Frenking, G
    [J]. COORDINATION CHEMISTRY REVIEWS, 2000, 197 : 249 - 276
  • [10] Boron in the coordination spheres of three transition-metal atoms: Syntheses and structures of metalloborylenes stabilized by a transition-metal base
    Braunschweig, H
    Radacki, K
    Rais, D
    Seeler, F
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (07) : 1066 - 1069
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