Process of pore pressure diffusion in saturated clay soil and impact of adsorbed water

Water molecules are adsorbed onto the surface and interlayer of clay minerals and form a film, which causes that pore pressure diffusion in clayey soils differs from that in granular material. In this paper, adsorbed water is classified into strongly adsorbed water and loosely adsorbed water, which provide a better understanding of the physical mechanisms of the adsorbed water. To investigate the impact of adsorbed water on pore pressure diffusion, a series laboratory tests were conducted, including the uplift pressure test, pore pressure diffusion test and adsorbed water content test. The experimental results implies that strongly adsorbed water can neither flow nor participate in pressure diffusion, but loosely adsorbed water shears at pressure gradients and participates in laminar flow. Therefore, as long as the dense clayey soil contains loosely adsorbed water, the pore pressure change at a local site can diffuse throughout the material. A concept called "loosely adsorbed water index (I-10) is defined to characterize both the content and physical properties of loosely adsorbed water: (1) when I-10 >= 1, the peripheral water molecules of loosely adsorbed water layer essentially behave the same as free water; (2) as I-10 -> 0, the physical properties of adsorbed water may evolve from a gel-like state to a solid-like state (strongly adsorbed water). According to the density of clay and the content of adsorbed water, the process of pore pressure diffusion can be divided into three modes: flow channels of free fluid, deformations of the adsorbed water layer and shear motions of the peripheral-adsorbed water molecules. Pore pressure response to additional water pressure strongly depends on the permeability, seepage path and boundary conditions. The time-lag effect of pore pressure diffusion should be considered in applications of effective stress in engineering.