Dampened circumrotation by CH•••π interactions in hydrogen bonded [2]rotaxanes

被引：37

作者：

Berna, Jose ^{[1
]}

Alajarin, Mateo ^{[1
]}

Martinez-Espin, Juan S. ^{[1
]}

Buriol, Lilian ^{[1
,2
]}

Martins, Marcos A. P. ^{[2
]}

Orenes, Raul-Angel ^{[3
]}

机构：

[1] Univ Murcia, Dept Quim Organ, Fac Quim, E-30100 Murcia, Spain

[2] Univ Fed Santa Maria, Dept Quim, BR-97105900 Santa Maria, RS, Brazil

[3] Univ Murcia, SAI, E-30100 Murcia, Spain

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 45期

关键词：

INTERMOLECULAR INTERACTIONS; ROTAXANES; MOTION; MACHINES; MONOMERS;

D O I：

10.1039/c2cc32092d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Establishment of CH center dot center dot center dot pi interactions between the aliphatic axis and the benzylic amide macrocycle of hydrogen-bonded [2]rotaxanes causes a measurable interference in the pirouetting submolecular motion of these interlocked molecules.

引用

页码：5677 / 5679

页数：3

共 32 条

[1] SCALES OF SOLUTE HYDROGEN-BONDING - THEIR CONSTRUCTION AND APPLICATION TO PHYSICOCHEMICAL AND BIOCHEMICAL PROCESSES [J].

ABRAHAM, MH .

CHEMICAL SOCIETY REVIEWS, 1993, 22 (02) :73-83

[2] Electrochemically switchable hydrogen-bonded molecular shuttles [J].

Altieri, A ;

Gatti, FG ;

Kay, ER ;

Leigh, DA ;

Martel, D ;

Paolucci, F ;

Slawin, AMZ ;

Wong, JKY .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (28) :8644-8654

[3] Interlocked and intertwined structures and superstructures [J].

Amabilino, DB ;

Stoddart, JF .

CHEMICAL REVIEWS, 1995, 95 (08) :2725-2828

[4]

Balzani V, 2000, ANGEW CHEM INT EDIT, V39, P3348, DOI 10.1002/1521-3773(20001002)39:19<3348::AID-ANIE3348>3.0.CO

[5]

2-X

[6]

Balzani V., 2011, NONCOVALENT ASSEMBLI, P159

[7] Influencing intramolecular motion with an alternating electric field [J].

Bermudez, V ;

Capron, N ;

Gase, T ;

Gatti, FG ;

Kajzar, F ;

Leigh, DA ;

Zerbetto, F ;

Zhang, SW .

NATURE, 2000, 406 (6796) :608-611

[8] Strategies and Tactics for the Metal-Directed Synthesis of Rotaxanes, Knots, Catenanes, and Higher Order Links [J].

Beves, Jonathon E. ;

Blight, Barry A. ;

Campbell, Christopher J. ;

Leigh, David A. ;

McBurney, Roy T. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (40) :9260-9327

[9] Bimodal dynamics of mechanically constrained hydrogen bonds revealed by vibrational photon echoes [J].

Bodis, Pavol ;

Yeremenko, Sergiy ;

Berna, Jose ;

Buma, Wybren J. ;

Leigh, David A. ;

Woutersen, Sander .

JOURNAL OF CHEMICAL PHYSICS, 2011, 134 (13)

[10] Photoinduction of fast, reversible translational motion in a hydrogen-bonded molecular shuttle [J].

Brouwer, AM ;

Frochot, C ;

Gatti, FG ;

Leigh, DA ;

Mottier, L ;

Paolucci, F ;

Roffia, S ;

Wurpel, GWH .

SCIENCE, 2001, 291 (5511) :2124-2128

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