Sublimation growth of bulk crystals of AlN-rich (AlN)x(SiC)1-x solid solutions

被引:5
作者
Bickermann, Matthias [1 ]
Filip, Octavian [1 ]
Epelbaum, Boris M. [1 ]
Heimann, Paul [1 ]
Winnacker, Albrecht [1 ]
机构
[1] Univ Erlangen Nurnberg, Dept Mat Sci 6, D-91058 Erlangen, Germany
来源
PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 7, NO 7-8 | 2010年 / 7卷 / 7-8期
关键词
AlN-SiC solution; growth from vapour; absorption; cathodoluminescence; QUALITY; SYSTEM;
D O I
10.1002/pssc.200983423
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
(AlN)(x)(SiC)(1-x) bulk single crystals are prepared by sublimation growth employing an AlN source placed in a tantalum carbide container. A 6H-SiC substrate acts both as seed and as source for silicon and carbon species. As the growth temperature is increased from 1900 degrees C to 2050 degrees C or the seed surface orientation is changed from (0115) to (0001), crystal coloration changes from yellowish to greenish to blackish. We attribute the change in coloration to an increasing Si/C content in the samples and estimate that up to 10% at of Si and C are incorporated. Accompanying changes in below band-gap optical absorption and cathodoluminescence are discussed. (C) 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
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页数:3
相关论文
共 13 条
[11]   Novel synthetic pathways to wide bandgap semiconductors in the Si-C-Al-N system [J].
Tolle, J ;
Roucka, R ;
Chizmeshya, AVG ;
Crozier, PA ;
Smith, DJ ;
Tsong, IST ;
Kouvetakis, J .
SOLID STATE SCIENCES, 2002, 4 (11-12) :1509-1519
[12]  
Yoder M. N., 1994, US Patent, Patent No. [5, 326, 992, 5326992]
[13]   PHASE-RELATIONSHIPS IN THE SILICON-CARBIDE ALUMINUM NITRIDE SYSTEM [J].
ZANGVIL, A ;
RUH, R .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1988, 71 (10) :884-890