PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 7, NO 7-8
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2010年
/
7卷
/
7-8期
关键词:
AlN-SiC solution;
growth from vapour;
absorption;
cathodoluminescence;
QUALITY;
SYSTEM;
D O I:
10.1002/pssc.200983423
中图分类号:
O4 [物理学];
学科分类号:
0702 ;
摘要:
(AlN)(x)(SiC)(1-x) bulk single crystals are prepared by sublimation growth employing an AlN source placed in a tantalum carbide container. A 6H-SiC substrate acts both as seed and as source for silicon and carbon species. As the growth temperature is increased from 1900 degrees C to 2050 degrees C or the seed surface orientation is changed from (0115) to (0001), crystal coloration changes from yellowish to greenish to blackish. We attribute the change in coloration to an increasing Si/C content in the samples and estimate that up to 10% at of Si and C are incorporated. Accompanying changes in below band-gap optical absorption and cathodoluminescence are discussed. (C) 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim