On the hydrolysis of 2,3-dihydro-1,3-di-tert-butyl-4,5-dimethylimidazol-2-ylidene.: The crystal structure of 1,3-di-tert-butyl-4,5-dimethylimidazolium bicarbonate [1]

被引：10

作者：

Abu-Rayyan, Ahmed

Abu-Salem, Qutaiba ^{[1
]}

Kuhn, Norbert ^{[1
]}

Maichle-Moessmer, Caecilia ^{[1
]}

Steimann, Manfred ^{[1
]}

Henkel, Gerald ^{[2
]}

机构：

[1] Univ Tubingen, Inst Anorgan Chem, D-72076 Tubingen, Germany

[2] Fachbereich Chem Univ, Paderborn, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2008年 / 634卷 / 05期

关键词：

carbenes; carbonates; hydrogen bonds; crystal structures;

D O I：

10.1002/zaac.200700576

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

1,3-Di-tert-butyl-4,5-dimethylimidazolium bicarbonate (7), formed on the exposure of 2,3-dihydro-1,3-di-tert-butyl-4,5-dimethylimidazol-2-ylidene (6) towards air, is prepared on the reaction of 6 with ammonium bicarbonate; its crystal structure analysis reveals the presence of dimeric bicarbonate anions linked to each other and to the imidazolium ions with hydrogen bonds.

引用

页码：823 / 824

页数：2

共 13 条

[1] Synthesis and crystal structure of the dichlorine adduct of 2,3-dihydro-1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene
Kuhn, N
Abu-Rayyan, A
Göhner, M
Steimann, M
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2002, 628 (08): : 1721 - 1723
[2] Nucleophilic Aromatic Substitution with 2,3-Dihydro-1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene
Mallah, Eyad
Kuhn, Norbert
Maichle-Moessmer, Caecilia
Steimann, Manfred
Stroebele, Markus
Zeller, Klaus-Peter
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2009, 64 (10): : 1176 - 1182
[3] Imidazole derivatives.: 47.: On the alkylation of 2,3-dihydro-1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene
Kuhn, N
Göhner, M
Steimann, M
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2002, 57 (06): : 631 - 636
[4] (Carb)2SnF4 (Carb=2,3-Dihydro-1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene - a Carbene Complex of Tetravalent Tin
Goehner, Martin
Herrmann, Florian
Kuhn, Norbert
Stroebele, Markus
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2012, 638 (14): : 2196 - 2199
[5] Rearrangement of a 5,7-di-tert-butyl-2-(quinolin-2-yl)-1,3-tropolone into a pentalene derivative
Sayapin, Yurii A.
Kolodina, Alexandra A.
Duong Nghia Bang
Gusakov, Evgeny A.
Dorogan, Igor, V
Komissarov, Vitaly N.
Borodkin, Gennadii S.
Tkachev, Valery V.
Duong Ngoc Toan
Vu Dinh Hoang
Tran Dai Lam
Shilov, Gennadii, V
Aldoshin, Serguei M.
Minkin, Vladimir, I
ARKIVOC, 2018, : 164 - 173
[6] Synthesis and properties of [Ph2(Carb)P]AlCl4 (Carb = 2,3-dihydro-1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene) -: a stable carbene complex of trivalent phosphorus
Kuhn, N
Fahl, J
Bläser, D
Boese, R
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1999, 625 (05): : 729 - 734
[7] {Ph2(Carb)P}MCl3 (M = Pd, Pt; Carb=2,3-dihydro-1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene) -: a novel cationic phosphane ligand
Kuhn, N
Göhner, M
Henkel, G
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1999, 625 (09): : 1415 - 1416
[8] Reaction of 1,3-dialkyl-4,5-dimethylimidazol-2-ylidenes with 2-bromo-2,3-dihydro-1H-1,3,2-diazaboroles (alkyl equals iPr and tBu)
Weber, L
Dobbert, E
Stammler, HG
Neumann, B
Boese, R
Blaser, D
CHEMISCHE BERICHTE-RECUEIL, 1997, 130 (06): : 705 - 710
[9] Conformational preferences of sterically congested 2-imidazolidinone using X-ray analysis and computational studies. Part 1: Trans-1-acetyl-4,5-di-tert-butyl-2-imidazolidinone
Abdel-Aziz, Alaa A. -M.
Al-Omar, Mohamed A.
El-Azab, Adel S.
Kunieda, Takehisa
JOURNAL OF MOLECULAR STRUCTURE, 2010, 969 (1-3) : 145 - 154
[10] Crystal structure of (E)-1,3-dimethyl-2-[3-(3-nitrophenyl)triaz-2-en-1- ylidene]-2,3-dihydro-1-Himidazole
Patil, Siddappa
Bugarin, Alejandro
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : 224 - +

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