Oxidative Polymerization of 3,6-Dianiline-2,5-dichlorobenzoquinone and Its Copolymerization with Aniline

被引：3
|
作者：
Kiseleva, S. G. [1 ]
Orlov, A. V. [1 ]
Bondarenko, G. N. [1 ]
Karpacheva, G. P. [1 ]
机构：
[1] Russian Acad Sci, Topchiev Inst Petrochem Synth, Moscow 119991, Russia
来源：
POLYMER SCIENCE SERIES B | 2018年 / 60卷 / 06期
关键词：
ELECTROCHEMICAL POLYMERIZATION; CHEMICAL POLYMERIZATION; CONDUCTING POLYMER; POLYANILINE FILMS; COMPOSITE; RING; PH;
D O I：
10.1134/S1560090418060076
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The oxidative polymerization of 3,6-dianiline-2,5-dichlorobenzoquinone is studied for the first time and it is shown that its reactivity in oxidation processes is higher than that of aniline. The influence of concentration, reagent ratio, and the acidity and temperature of reaction solution on the oxidation reaction is investigated. The specific features of polymerization of 3,6-dianiline-2,5-dichlorobenzoquinone determined by the presence of a chloranil substituent at the nitrogen atom are revealed. Poly(3,6-dianiline-2,5-dichlorobenzoquinone) has a highly ordered supramolecular structure. The copolymerization of 3,6-dianiline-2,5-dichlorobenzoquinone with aniline is studied, and it is found that the reaction kinetics and the degree of copolymer oxidation are determined by aniline content in the monomer mixture.
引用
收藏
页码：717 / 726
页数：10
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