Phosphonium Halides as Both Processing Additives and Interfacial Modifiers for High Performance Planar-Heterojunction Perovskite Solar Cells

被引:102
作者
Sun, Chen [1 ]
Xue, Qifan [1 ]
Hu, Zhicheng [1 ]
Chen, Ziming [1 ]
Huang, Fei [1 ]
Yip, Hin-Lap [1 ]
Cao, Yong [1 ]
机构
[1] S China Univ Technol, Inst Polymer Optoelect Mat & Devices, State Key Lab Luminescent Mat & Devices, Guangzhou 510640, Guangdong, Peoples R China
关键词
interfacial engineering; perovskite solar cells; planar heterojunctions; processing additives; HIGH-EFFICIENCY; CHARGE-TRANSPORT; TEMPERATURE; TRIHALIDE; LENGTHS; DYE; TIN;
D O I
10.1002/smll.201403344
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Organic halide salts are successfully incorporated in perovskite-based planar-heterojunction solar cells as both the processing additive and interfacial modifier to improve the morphology of the perovskite light-absorbing layer and the charge collecting property of the cathode. As a result, perovskite solar cells exhibit a significant improvement in power conversion efficiency (PCE) from 10% of the reference device to 13% of the modified devices. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:3344 / 3350
页数:7
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