Cobalt-catalyzed O-arylation of N-protected amino alcohols with arenes via cross-dehydrogenative C-O coupling strategy: Direct access to aryloxyamines

被引：4

作者：

Wang, Chaoyu ^{[1
]}

Bei, Wenfeng ^{[1
]}

Li, Wanting ^{[1
]}

Wang, Dongwei ^{[1
]}

Liu, Yuqin ^{[1
]}

Gong, Zile ^{[1
]}

Zeng, Kailin ^{[1
]}

Feng, Ruokun ^{[1
]}

Huang, Xianqiang ^{[2
]}

Qi, Chenze ^{[1
,3
]}

机构：

[1] Shaoxing Univ, Coll Chem & Chem Engn, Res Ctr Adv Catalyt Mat & Funct Mol Synth, Zhejiang Key Lab Alternat Technol Fine Chem Proc, Shaoxing 312000, Peoples R China

[2] Liaocheng Univ, Sch Chem & Chem Engn, Shandong Prov Key Lab Chem Energy Storage & Novel, Liaocheng 252059, Peoples R China

[3] Jiamusi Univ, Sch Pharm, Jiamusi 154007, Heilongjiang, Peoples R China

来源：

TETRAHEDRON LETTERS | 2022年 / 106卷

关键词：

Cobalt; -catalyzed; Amino alcohols; C -H arylation; Bidentate-chelation; Aryloxyamines; AROMATIC NUCLEOPHILIC-SUBSTITUTION; VITRO DNA-BINDING; H ALKOXYLATION; 1-NAPHTHYLAMINE DERIVATIVES; SHISHIDIDEMNIOLS; REARRANGEMENT; ACTIVATION; AMINATION; TUNICATE; COMPLEX;

D O I：

10.1016/j.tetlet.2022.154062

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient Co(II)-catalyzed cross-dehydrogenative C-O coupling strategy for the arylation of N-protected amino alcohols, including 1,2-, 1,3-and 1,4-amino alcohols, branched amino alcohols and cyclic amino alcohols with different amides derivatives has been developed, affording a wide range of corresponding aryloxyamines compounds with excellent convertibility in moderate to good yields, which are of great interest in medicinal and pharmaceutical chemistry. Furthermore, this reaction system could be further applied to the preparation of potential bioactive molecules. CO 2022 Elsevier Ltd. All rights reserved.

引用

页数：5

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