Electron hopping interactions in amorphous ZnO films probed by x-ray absorption near edge structure analysis

被引:7
作者
Cho, Deok-Yong [1 ,3 ]
Kim, Jeong Hwan [2 ]
Hwang, Cheol Seong [2 ]
机构
[1] Seoul Natl Univ, CSCMR, Seoul 151747, South Korea
[2] Seoul Natl Univ, WCU Hybrid Mat Program, Dept Mat Sci & Engn, Interuniv Semicond Res Ctr, Seoul 151744, South Korea
[3] Seoul Natl Univ, FPRD, Dept Phys & Astron, Seoul 151747, South Korea
关键词
ZINC-OXIDE;
D O I
10.1063/1.3596701
中图分类号
O59 [应用物理学];
学科分类号
摘要
The x-ray absorption near edge structures of amorphous ZnO (a-ZnO) films were examined. The near-edge structure, which reflects the virtual electron hopping interactions in the photoabsorption final states, increased in intensity compared to crystalline ZnO. Theoretical path-by-path analyses revealed that this reflects the extinction of the multiple hopping processes found in paths such as Zn -> O -> O'-> Zn or Zn -> O -> Zn'-> Zn while the Zn-(O or Zn) hopping interactions remain. This suggests that the structural disorders in a-ZnO can induce the localization of the conduction band through the limited hopping interactions. (C) 2011 American Institute of Physics. [doi: 10.1063/1.3596701]
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收藏
页数:3
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