One-dimensional co-ordination polymers formed by crown ether metal cation bridges:: synthesis and crystal structure of nickel(II) dithiolene complexes [{Na(benzo-15-crown-5)}2 Ni(i-mnt)2]n•nCH2Cl2 and [{Na(benzo-15-crown-5)}2Ni(mnt)2]n

被引：38

作者：

Long, DL ^{[1
]}

Cui, Y ^{[1
]}

Chen, JT ^{[1
]}

Cheng, WD ^{[1
]}

Huang, JS ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

来源：

POLYHEDRON | 1998年 / 17卷 / 22期

基金：

中国国家自然科学基金;

关键词：

crown ether; nickel(II) dithiolate; crystal structure; co-ordination polymer;

D O I：

10.1016/S0277-5387(98)00195-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of NiCl2. 6H(2)O, Na-2[i-mnt] and benzo-15-crown-5 in CH3OH/CH2Cl2 at room temperature leads to [{Na(benzo-15-crown-5)}(2)Ni(mnt)(2)](n) . nCH(2)Cl(2) (1). The same reaction with Na-2[mnt] instead of Na-2[i-mnt] affords [{Na(benzo-15-crown-5)}(2)Ni(mnt)(2)](n) (2). Both complexes were isolated as crystalline products. X-ray diffraction analyses reveal that the main segments of 1 and 2 are infinite "train" structures, in which the building blocks Ni(i-mnt), or Ni(mnt), in end-to-end arrangements act as "body frames" and crown cycles standing by the body frames play the role of "cartwheel". They are joined with each other through sodium ions. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：3969 / 3975

页数：7

共 36 条

[21] A NOVEL SQUARE-PLANAR CD(II) WITH 4 SULFUR DONOR LIGANDS - CRYSTAL-STRUCTURE AND CD-113 NMR
LI, HY
AMMA, EL
[J]. INORGANICA CHIMICA ACTA, 1990, 177 (01) : 5 - 7
[22] LIU CW, 1996, J CLUST SCI, V7, P385
[23] LONG D, IN PRESS
[24] Synthesis and characterization of isomanolonitrile dithiolato palladium complexes. Crystal structure of (PPh3)(2)Pd(S2C4N2) and (Et4N)(2)WS4Pd(S2C4N2)
Long, DL
Zheng, H
Xin, XQ
Sakane, G
Shibahara, T
[J]. POLYHEDRON, 1997, 16 (24) : 4305 - 4311
[25] Bis(2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-pentaoxabenzo[b]cyclopentadecene-O-1,O-4,O-7,O-10,O-13)sodium(1+) 1,1,7,7-tetracyano-3,5-dithiahepta-1,6-diene-2,6-dithiolate(2-) (2/1)
Long, DL
Jin, QH
Xin, XQ
Yu, KB
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1997, 53 : 554 - 556
[26] LONG DL, 1988, CHEM LETT, P171
[27] HYDROGEN-BONDS IN SCHLIPPES SALT - REFINEMENT OF THE CRYSTAL-STRUCTURES OF NA3SBS4.9H2O BY X-RAY-DIFFRACTION AND NA3SBS4.9D2O BY NEUTRON-DIFFRACTION AT ROOM-TEMPERATURE
MEREITER, K
PREISINGER, A
GUTH, H
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1979, 35 (JAN): : 19 - 25
[28] MILLER JS, 1975, PROGR INORG CHEM, V20, P1
[29] MOODY DC, 1979, CRYST STRUCT COMMUN, V8, P933
[30] CRYSTAL-STRUCTURES OF COMPLEXES BETWEEN ALKALI-METAL SALTS AND CYCLIC POLYETHERS .11. COMPLEXES FORMED BETWEEN 2,3,5,6,8,9,11,12-OCTAHYDRO-1,4,7,10,13-BENZOPENTAOXACYCLOPENTADECIN (BENZO-15-CROWN-5) AND SODIUM-PERCHLORATE (1-1), SODIUM-PERCHLORATE (2-1), AND SODIUM TETRAPHENYLBORATE (2-1)
OWEN, JD
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (07): : 1066 - 1075

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