Alkali activated slag cements using waste glass as alternative activators. Rheological behaviour

被引:79
作者
Torres-Carrasco, Manuel [1 ]
Rodriguez-Puertas, Carlos [1 ]
del Mar Alonso, Maria [1 ]
Puertas, Francisca [1 ]
机构
[1] CSIC, Eduardo Torroja Inst Construct Sci IETcc, Madrid, Spain
来源
BOLETIN DE LA SOCIEDAD ESPANOLA DE CERAMICA Y VIDRIO | 2015年 / 54卷 / 02期
关键词
Waste glass; Alternative activators; Alkali-activated materials; Rheology; Yield stress; MECHANICAL STRENGTH; FLY-ASH; EMISSIONS; MORTARS; ADMIXTURES;
D O I
10.1016/j.bsecv.2015.03.004
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The purpose of this study is to investigate news activators in the preparation of alkali-activated materials (AAMs) alternative to Portland cements by reusing waste glass. Alkali-activated blast furnace slag (AAS) constitutes an alternative to Portland cement due to high energy and environmental pollution associated with industrial Portland cement. Moreover, alkali activated materials offer a series of higher properties than ordinary Portland cement (OPC), such as better strength and durability behaviour. However, the rheology of these materials has been much less intensely researched. The present study aimed to study the effect of waste glass as activator and as replacement of blast furnace slag on the rheological behaviour of AAS pastes, with a comparison between the rheological parameters and fluidity of these pastes to the same parameters in standard cements (CEM I and CEM III/B). The findings show that AAS paste behaviour of rheology when the activator was a commercial waterglass solution or NaOH/Na2CO3 with waste glass was similar, fit the Herschel-Bulkley model. The formation of primary C-S-H gel in both cases were confirmed. However, the rheological behaviour in standard cements fit the Bingham model. The use of the waste glass may be feasible from a rheological point of view in pastes can be used. (C) 2015 Sociedad Espanola de Ceramica y Vidrio. Published by Elsevier Espana, S.L.U.
引用
收藏
页码:45 / 57
页数:13
相关论文
共 43 条
[1]   A review on emission analysis in cement industries [J].
Ali, M. B. ;
Saidur, R. ;
Hossain, M. S. .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2011, 15 (05) :2252-2261
[2]  
Alonso MM, 2007, MATER CONSTRUCC, V57, P65
[3]   Application of a system dynamics approach for assessment and mitigation of CO2 emissions from the cement industry [J].
Anand, Shalini ;
Vrat, Prem ;
Dahiya, R. P. .
JOURNAL OF ENVIRONMENTAL MANAGEMENT, 2006, 79 (04) :383-398
[4]  
[Anonymous], 1993, CEMENT CONCRETE RES
[5]  
Boden T., 2011, Global CO2 emissions from fossil fuel burning, cement manufacture, and gas flaring: 1751-2008
[6]   Production and usage of powdered alkali metal silicate hydrates [J].
Brykov, A. S. ;
Korneev, V. I. .
METALLURGIST, 2008, 52 (11-12) :648-652
[7]  
C.T. Roadmap, 2010, WORLD BUSINESS COUNC
[8]   Environmental impact of cement production: detail of the different processes and cement plant variability evaluation [J].
Chen, C. ;
Habert, G. ;
Bouzidi, Y. ;
Jullien, A. .
JOURNAL OF CLEANER PRODUCTION, 2010, 18 (05) :478-485
[9]   Effect of the Sio2/Na2O ratio on the alkali activation of fly ash.: Part II:: 29Si MAS-NMR Survey [J].
Criado, M. ;
Fernandez-Jimenez, A. ;
Palomo, A. ;
Sobrados, I. ;
Sanz, J. .
MICROPOROUS AND MESOPOROUS MATERIALS, 2008, 109 (1-3) :525-534
[10]   Rietveld quantitative amorphous content analysis [J].
De La Torre, AG ;
Bruque, S ;
Aranda, MAG .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2001, 34 :196-202