Hydrothermal synthesis and crystal structure of a three-dimensional vanadium tellurite V4Te4O18

被引：27
|
作者：
Xiao, DR [1 ]
Wang, ST [1 ]
Wang, EB [1 ]
Hou, Y [1 ]
Li, YG [1 ]
Hu, CW [1 ]
Xu, L [1 ]
机构：
[1] NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Jilin, Peoples R China
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2003年 / 176卷 / 01期
基金：
中国国家自然科学基金;
关键词：
vanadium tellurite; three-dimensional framework; hydrothermal synthesis; crystal structure;
D O I：
10.1016/S0022-4596(03)00381-5
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel vanadium tellurite V4Te4O18 was synthesized by the hydrothermal reaction Of V2O5, Na2TeO3, CuCl2.6H(2)O, and water. Its structure was determined by elemental analyses, XPS spectra, TG analysis, IR spectrum and the single-crystal X-ray diffraction. The title compound crystallized in monoclinic system, space group P2(1)/c, a = 7.2475(14) Angstrom b = 9.4901(19) Angstrom, c = 10.073(2) Angstrom7 beta = 94.45(3)degrees, V = 690.7(2) Angstrom, Z = 2, lambda(MoKalpha) = 0.71073 Angstrom, (R(F) = 0.0316 for 1580 reflections). Data were collected on a Rigaku R-AXIS RAPID IP diffractometer at 293 K in the range of 2.82 < theta < 27.47degrees. The title compound exhibits a novel three-dimensional (313) framework, formed by VO6 octahedra, VO5 square pyramids, TeO4 folded squares, and TeO5 square pyramids via the corner- and/or edge-sharing mode. The 3D framework consists of two different types of one-dimensional (I D) tunnels parallel to a-axes. (C) 2003 Elsevier Inc. All rights reserved.
引用
收藏
页码：159 / 164
页数：6
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