Olivine LiFePO4: the remaining challenges for future energy storage

被引:471
作者
Wang, Jiajun [1 ]
Sun, Xueliang [1 ]
机构
[1] Univ Western Ontario, Dept Mech & Mat Engn, London, ON N6A 5B9, Canada
基金
加拿大创新基金会; 加拿大自然科学与工程研究理事会;
关键词
LITHIUM IRON PHOSPHATE; SODIUM-ION BATTERIES; HIGH-PERFORMANCE CATHODE; ENHANCED ELECTROCHEMICAL PERFORMANCE; HYDROTHERMALLY SYNTHESIZED LIFEPO4; SOLID-SOLUTION PHASES; LI-ION; IN-SITU; ELECTRODE MATERIALS; AMORPHOUS FEPO4;
D O I
10.1039/c4ee04016c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Rechargeable batteries can effectively store electrical energy as chemical energy, and release it when needed, providing a good choice for applications in electric vehicles (EVs). Naturally, safety concerns are the key issue for the application of battery technology in EVs. Olivine LiFePO4 is considered to be the most promising cathode material for lithium-ion batteries due to its environmental friendliness, high cycling performance and safety characteristics. Some important breakthroughs in recent years have allowed its successful commercialization. However, in spite of its success, the commercial application of LiFePO4 batteries in EVs is still hindered by some technological obstacles. Herein, we provide an update on our previous review, and overview the most significant advances in the remaining challenges for this promising battery material. New research directions and future trends have also been discussed.
引用
收藏
页码:1110 / 1138
页数:29
相关论文
共 248 条
[61]   Temperature Dependence of Aliovalent-Vanadium Doping in LiFePO4 Cathodes [J].
Harrison, Katharine L. ;
Bridges, Craig A. ;
Paranthaman, Mariappan Parans ;
Segre, Carlo U. ;
Katsoudas, John ;
Maroni, Victor A. ;
Idrobo, Juan Carlos ;
Goodenough, John B. ;
Manthiram, Arumugam .
CHEMISTRY OF MATERIALS, 2013, 25 (05) :768-781
[62]   Sodium-Ion Battery based on an Electrochemically Converted NaFePO4 Cathode and Nanostructured Tin-Carbon Anode [J].
Hasa, Ivana ;
Hassoun, Jusef ;
Sun, Yang-Kook ;
Scrosati, Bruno .
CHEMPHYSCHEM, 2014, 15 (10) :2152-2155
[63]   Nano-network electronic conduction in iron and nickel olivine phosphates [J].
Herle, PS ;
Ellis, B ;
Coombs, N ;
Nazar, LF .
NATURE MATERIALS, 2004, 3 (03) :147-152
[64]   Structure and Electrochemistry of Vanadium-Modified LiFePO4 [J].
Hong, Jian ;
Wang, Xiao-Liang ;
Wang, Qi ;
Omenya, Fredrick ;
Chernoya, Natasha A. ;
Whittingham, M. Stanley ;
Graetz, Jason .
JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (39) :20787-20793
[65]   Charge carriers in rechargeable batteries: Na ions vs. Li ions [J].
Hong, Sung You ;
Kim, Youngjin ;
Park, Yuwon ;
Choi, Aram ;
Choi, Nam-Soon ;
Lee, Kyu Tae .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (07) :2067-2081
[66]   Amorphous FePO4 as 3 V cathode material for lithium secondary batteries [J].
Hong, YS ;
Ryu, KS ;
Park, YJ ;
Kim, MG ;
Lee, JM ;
Chang, SH .
JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (06) :1870-1874
[67]   Graphene-modified LiFePO4 cathode for lithium ion battery beyond theoretical capacity [J].
Hu, Lung-Hao ;
Wu, Feng-Yu ;
Lin, Cheng-Te ;
Khlobystov, Andrei N. ;
Li, Lain-Jong .
NATURE COMMUNICATIONS, 2013, 4
[68]   Approaching theoretical capacity of LiFePO4 at room temperature at high rates [J].
Huang, H ;
Yin, SC ;
Nazar, LF .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2001, 4 (10) :A170-A172
[69]   The influence of temperature on a nutty-cake structural material: LiMn1-xFexPO4 composite with LiFePO4 core and carbon outer layer for lithium-ion battery [J].
Huo, Zhen-Qing ;
Cui, Yu-Ting ;
Wang, Dan ;
Dong, Yue ;
Chen, Li .
JOURNAL OF POWER SOURCES, 2014, 245 :331-336
[70]   Atomic-scale investigation of defects, dopants, and lithium transport in the LiFePO4 olivine-type battery material [J].
Islam, MS ;
Driscoll, DJ ;
Fisher, CAJ ;
Slater, PR .
CHEMISTRY OF MATERIALS, 2005, 17 (20) :5085-5092