In situ construction of metal-organic sulfur-containing heterocycle frameworks

被引：101
作者：
Zhu, Hai-Bin [1 ,2 ,3 ]
Gou, Shao-Hua [1 ,2 ,3 ]
机构：
[1] Southeast Univ, Pharmaceut Res Ctr, Nanjing 211189, Peoples R China
[2] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Peoples R China
[3] Jiangsu Prov Hitech Key Lab Biomed Res, Nanjing 211189, Peoples R China
来源：
COORDINATION CHEMISTRY REVIEWS | 2011年 / 255卷 / 1-2期
基金：
中国国家自然科学基金;
关键词：
In situ methods; Sulfur-containing heterocycle; S-S function reaction; C-S bond cleavage; Thiol-S atom reaction; S BOND-CLEAVAGE; COORDINATION POLYMERS; DISULFIDE CLEAVAGE; CRYSTAL-STRUCTURES; ELECTRON-TRANSFER; LIGAND; COMPLEXES; REDOX; COPPER(II); REACTIVITY;
D O I：
10.1016/j.ccr.2010.09.011
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This review outlines three types of in situ methods used for constructing metal-organic sulfur-containing heterocycle frameworks, viz., in situ S-S function reactions, in situ C-S bond cleavage and in situ thiol-S atom reactions. Each method is described in detail in three respects, namely (i) reaction parameters, (ii) the organic transformation and coordination modes involved, and (iii) fascinating structures and functional properties of those in situ-generated metal-coordination compounds. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：318 / 338
页数：21
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