Tris(triorganostannyltetrazoles): Synthesis and supramolecular structures

被引：77

作者：

Hill, M ^{[1
]}

Mahon, MF ^{[1
]}

Molloy, KC ^{[1
]}

机构：

[1] UNIV BATH,SCH CHEM,BATH BA2 7AY,AVON,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 09期

关键词：

D O I：

10.1039/dt9960001857

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Six trifunctional triorganotin tetrazoles, (R(3)SnN(4)CCH(2)CH(2))(3)C(NO2) and 1,3,5-(R(3)SnN(4)C)(3)C6H3 (R = Me, Et or Bu), have been synthesised by a cycloaddition route from SnR(3)(N-3) and either (NCCH2CH2)(3)C(NO2) or 1,3,5-(NC)(3)C6H3 as dipolarophile. The compounds have been characterised by H-1, C-13, Sn-119 NMR and (119)Mossbauer spectroscopies, while the crystal structures of the tributyltin examples of each series reveal they adopt layered supramolecular arrays.

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页码：1857 / 1865

页数：9

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